30737-85-0Relevant articles and documents
Total synthesis of aspinolide B: a ring-closing metathesis approach
Ghosh, Subhash,Rao, R. Vengal
, p. 6937 - 6940 (2007)
A highly convergent stereoselective total synthesis of aspinolide B, a 10-membered lactone is described. The key step includes a ring-closing metathesis reaction to construct the 10-membered ring and the E-olefinic moiety. d-Mannitol was used as a chiral
The Baylis-Hillman reaction: a strategic tool for the synthesis of higher-carbon sugars
Radha Krishna, Palakodety,Narasimha Reddy,Sreeshailam,Uday Kiran,Jagdeesh
, p. 6466 - 6470 (2008/02/12)
The Baylis-Hillman reaction of acyclic sugar-derived aldehydes is invoked as an attractive synthetic strategy for ready access to higher-carbon sugars.
THE ISOPROPYLIDENATION OF D-RIBOSE DIETHYL DITHIOACETAL AND RIBITOL. A NEW SYNTHESIS OF α- AND β-D-RIBOFURANOSYLETHYNE via 2,3:4,5-DI-O-ISOPROPYLIDENE-aldehydo-D-RIBOSE
Aslani-Shotorbani, Gaffar,Buchanan, J. Grant,Edgar, Alan R.,Shahidi, Parvin K.
, p. 37 - 52 (2007/10/02)
The reaction of D-ribose diethyl dithioacetal with acetone and sulphuric acid in the presence of anhydrous copper sulphate gives the 2,3:4,5-di-O-isopropylidene derivative 14 (40percent) and the isomeric 2,5:3,4-di-O-isopropylidene acetal 17 (40percent),