3075-84-1Relevant articles and documents
Mechanism of Oxidation of Methylbenzenes by Palladium(II) in Trifluoroacetic Acid. One-electron Transfer and Electrophilic Substitution
Kozhevnikov, Ivan V.,Kim, Vladimir I.,Talzi, Eugeni P.,Sidelnikov, Vladimir N.
, p. 1392 - 1394 (1985)
The oxidation of methylbenzenes by Pd(II) in CF3CO2H to give diarylmethanes has been shown to occur via a one-electron transfer mechanism.
Direct hydroxylation of p-xylene to 2,5-xylenol with hydroxylamine in ionic liquids/molybdenum catalytic system
Zhang,Gao,Jin,Xue,Zhao,Wang,Wang
, p. 7527 - 7531 (2015/02/02)
Direct hydroxylation of p-xylene to 2,5-xylenol with hydroxylamine was carried out in an ionic liquids/molybdenum catalytic system. High 2,5-xylenol selectivity (80-98 %) can be achieved with good p-xylene conversion (5.9-9.9 %) in this catalytic system. The recycling experiments suggested the ionic liquids/molybdenum catalytic system was stable enough to be recycled for the hydroxylation reaction.
Gold(III)-catalyzed direct acetoxylation of arenes with iodobenzene diacetate
Qiu, Di,Zheng, Zhitong,Mo, Fanyang,Xiao, Qing,Tian, Yu,Zhang, Yan,Wang, Jianbo
supporting information; experimental part, p. 4988 - 4991 (2011/11/13)
AuCl3-catalyzed direct acetoxylation of electron-rich aromatic compounds has been achieved with iodobenzene diacetate as the acetoxylation reagent.