30824-25-0

Basic information

• Product Name: 1-Propanamine, N,N-bis[2-(diphenylphosphino)ethyl]-
• CAS NO: 30824-25-0
• Molecular Formula: C31H35NP2
• Molecular Weight: 483.573
• Mol File: 30824-25-0.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: 1-Propanamine, N,N-bis[2-(diphenylphosphino)ethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: 1-Propanamine, N,N-bis[2-(diphenylphosphino)ethyl]-(30824-25-0)
• EPA Substance Registry System: 1-Propanamine, N,N-bis[2-(diphenylphosphino)ethyl]-(30824-25-0)

Safety Data

• Hazardous Substances Data: 30824-25-0(Hazardous Substances Data)

Usage

Molecular Weight

Not provided

+ State

Not provided

+ Color

Not provided

+ Melting Point

Not provided

+ Boiling Point

Not provided

+ Solubility

Not provided

+ Functional Groups

Amine, Phosphine

+ Reactivity

Acts as a ligand in coordination chemistry

+ Uses

Used in the synthesis of metal complexes with various applications in catalysis, such as in the production of pharmaceuticals and fine chemicals

+ Central Molecule

Propanamine

+ Attached Arms

Two 2-(diphenylphosphino)ethyl arms

+ Unique Structure

Yes

+ Valuable for a wide range of chemical reactions and processes

Yes

Upstream product

• 6735-35-9 2,2'-(n-propylimino)bisethanol 
• 2096-78-8 vinyldiphenylphosphine oxide 

Downstream Products

• 149132-88-7 nitridodichloro(bis(diphenylphosphinoethyl)propylamine)technetium(V) 
• 147106-49-8 mer,trans-[(CH₃CH₂CH₂N(CH₂CH₂PPh₂)2)RuCl₂(PPh₃)] 
• 147106-72-7 {trans,mer-RuCl₂(PNP)(S-DMSO)} 
• 130574-11-7 {(N,N-bis(2-(diphenylphosphino)ethyl)-n-propylamine)Ir(η4-cycloocta-1,5-diene)}BPh4 
• 1181844-48-3 fac-[TcCl₂(NO)(bis[(2-diphenylphosphino)propyl]amine)] 
• 1181844-48-3 mer-[TcCl₂(NO)(bis[(2-diphenylphosphino)propyl]amine)] 

Relevant articles and documents

Novel clamp metal complex and application thereof

The invention discloses a method for preparing a novel clamp-shaped complex and application of the novel clamp-shaped complex in the reaction of catalytic hydrogenation of carboxylic acid ester compounds to produce corresponding alcohols and reaction of carbon dioxide catalytic hydrogenation to form formamide compounds. Carboxylic acid esters and hydrogen as raw materials or carbon dioxide, hydrogen and amine compounds as raw materials are reacted in an organic solvent condition or a solvent-free condition in the presence of a transition metal complex as a catalyst to respectively form the corresponding alcohol compounds and/or corresponding formamide compounds. The method has the advantages of being high in reaction efficiency, good in selectivity, mild in conditions, economical, environmentally-friendly, and simple in operation, and has good promotion and application prospects.

Scope and limitations of the preparation of aminophosphines R-NH(CH2CH2PPH2) and aminodiphosphines R-N(CH2CH2PPH2)2 via Michael addition of amines to vinylphosphines

The addition of a range of amines to vinyldiphenylphosphine oxide was examined under different reaction conditions. The methodology provides mixed phosphorus-nitrogen donor ligands R-NH(CH2CH2PPh2) 3 and R-N(CH2CH2PPh2)2 4, which could be prepared in high yields and purity in two simple steps. Labelling study revealed a non-concerted mechanism and the X-ray crystal structure of 1e is reported.