3088-15-1

Basic information

• Product Name: 4,6-DIBENZOYLRESORCINOL
• Synonyms: 4,6-DIBENZOYLRESORCINOL;1,3-Dibenzoyl-4,6-dihydroxybenzene;5-Benzoyl-2,4-dihydroxybenzophenone;6-dibenzoylresorcinol;Methanone, 1,1'-(4,6-dihydroxy-1,3-phenylene)bis[1-phenyl-
• CAS NO: 3088-15-1
• Molecular Formula: C₂₀H₁₄O₄
• Molecular Weight: 318.32
• Mol File: 3088-15-1.mol
• Article Data: 6

Chemical Properties

• Melting Point: 150℃
• Boiling Point: 549.6 °C at 760 mmHg
• Flash Point: 300.2 °C
• Appearance: /
• Density: 1.312
• Vapor Pressure: 1.09E-12mmHg at 25°C
• Refractive Index: 1.66
• PKA: 5.62±0.48(Predicted)
• CAS DataBase Reference: 4,6-DIBENZOYLRESORCINOL(CAS DataBase Reference)
• NIST Chemistry Reference: 4,6-DIBENZOYLRESORCINOL(3088-15-1)
• EPA Substance Registry System: 4,6-DIBENZOYLRESORCINOL(3088-15-1)

Safety Data

• Hazardous Substances Data: 3088-15-1(Hazardous Substances Data)

Usage

Preparation

Preparation by saponification of 4,6-di-–(benzoyloxy)-1,3-dibenzoylbenzene (SM) with potassium hydroxide in refluxingethanol The keto ester SM was obtained by acylation of resorcinol dibenzoate with benzoyl chloride in the presence of zinc chloride at 100–120° during several days.

InChI:InChI=1/C20H14O4/c21-17-12-18(22)16(20(24)14-9-5-2-6-10-14)11-15(17)19(23)13-7-3-1-4-8-13/h1-12,21-22H

Upstream product

• 103282-18-4 1,5-dibenzoyl-2,4-bis-benzoyloxy-benzene 
• 94-01-9 resorcinol dibenzoate 
• 98-88-4 benzoyl chloride 
• 151-10-0 1,3-Dimethoxybenzene 
• 119-53-9 2-hydroxy-2-phenylacetophenone 
• 122118-04-1 2,3,5,6-Tetraphenylbenzo<1,2-b:5,4-b'>difuran 
• 108-46-3 recorcinol 

Downstream Products

• 163770-79-4 1-Hydroxy-3-<(4-cyanobenzyl)oxy>-4,6-dibenzoylbenzene 
• 163770-81-8 1,3-Bis(benzyloxy)-4,6-dibenzoylbenzene 
• 163770-82-9 1,3-Bis<(4-cyanobenzyl)oxy>-4,6-dibenzoylbenzene 
• 163770-83-0 1,3-Bis<(4-methoxybenzyl)oxy>-4,6-dibenzoylbenzene 
• 163770-84-1 1,3-Bis<(3,5-dimethoxybenzyl)oxy>-4,6-dibenzoylbenzene 
• 436812-46-3 [5-benzoyl-2,4-bis-(8-bromo-octyloxy)-phenyl]-phenyl-methanone 
• 436812-50-9 [5-benzoyl-2,4-bis-(12-bromo-dodecyloxy)-phenyl]-phenyl-methanone 
• 833485-57-7 (2,4-dibenzoyl-5-cyanomethoxy-phenoxy)-acetonitrile 
• 1027079-23-7 2,6-bis-(7-bromo-heptyl)-3,5-diphenyl-2,3,5,6-tetrahydro-benzo[1,2-b;5,4-b']difuran-3,5-diol 
• 436812-47-4 2,6-bis-(7-bromo-heptyl)-3,5-diphenyl-benzo[1,2-b;5,4-b']difuran 

Relevant articles and documents

Reversible-irreversible approach to schiff base macrocycles: Access to isomeric macrocycles with multiple salphen pockets

We have developed methodology for the formation of a new family of metal-free Schiff base macrocycles utilizing the differential exchange rates of aldimines and ketimines. The more robust ketimine bond Is kinetically Inert under the milder conditions used for aldimine bond formation. In particular, this route enables access to the first conjugated macrocycles with four unsymmetrical N2O2 salphen-like pockets.

Synthesis of novel cyclophanes containing both benzo[1,2-b:5,4-b']difuran and naphthalene rings

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