30930-83-7

Basic information

• Product Name: Cyclohexanamine, N-hexylidene-
• CAS NO: 30930-83-7
• Molecular Formula: C12H23N
• Molecular Weight: 181.321
• Mol File: 30930-83-7.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: Cyclohexanamine, N-hexylidene-(CAS DataBase Reference)
• NIST Chemistry Reference: Cyclohexanamine, N-hexylidene-(30930-83-7)
• EPA Substance Registry System: Cyclohexanamine, N-hexylidene-(30930-83-7)

Safety Data

• Hazardous Substances Data: 30930-83-7(Hazardous Substances Data)

Upstream product

• 109-69-3 n-Butyl chloride 
• 113832-57-8 N-ethylidenecyclohexylamine 
• 108-91-8 cyclohexylamine 
• 66-25-1 hexanal 
• 10264-27-4 N-cyclohexylhexanamide 
• 693-02-7 hex-1-yne 
• 931-53-3 Cyclohexyl isocyanide 
• 109-66-0 pentane 
• 111-27-3 hexan-1-ol 

Downstream Products

• 65080-75-3 3-cyclohexyl-4-pentyl-oxazolidine 
• 30857-37-5 n-Butyl-2-phenyl-4-butanal-cyclohexylimin 
• 30857-71-7 n-Butyl-2-phenyl-4-butanal 
• 130111-46-5 5-(1-butyl)-1-phenylsulfonyl-1,6,7,8-tetrahydrocyclopentindole 
• 130111-51-2 2-[2-(1-Benzenesulfonyl-1H-pyrrol-2-yl)-cyclopent-(E)-ylidene]-hexanal 
• 130111-52-3 2-[2-(1-Benzenesulfonyl-1H-pyrrol-2-yl)-1-hydroxy-cyclopentyl]-hexanal 
• 4746-28-5 N-hexylcyclohexanamine 
• 30857-70-6 2-benzylhexanal 
• 123-05-7 d,l-2-ethylhexanal 
• 30857-31-9 (2-butyl-pent-4-enylidene)-cyclohexyl-amine 
• 30930-91-7 Ethyl-2-hexanal-cyclohexylimin 
• 30857-35-3 Benzyl-2-hexanal-cyclohexylimin 
• 66-25-1 hexanal 
• 30857-33-1 (2-butyl-hexylidene)-cyclohexyl-amine 

Relevant articles and documents

A BEt3-Base Catalyst for Amide Reduction with Silane

Reported herein is the development of a simple but practical catalytic system for the selective reduction of amides with hydrosilane or hydrosiloxane. Low-cost and readily available triethylborane (1.0 M in THF), in combination with a catalytic amount of an alkali metal base, was found to catalyze the reduction of all three amide classes (tertiary, secondary, and primary amides) to form amines under mild conditions. In addition, the selective transformation of secondary amides to aldimines and primary amides to nitriles can also be achieved by using a proper combination of BEt3 and base. The scope of these BEt3-base-catalyzed amide hydrosilylation reactions has been explored in depth. Preliminary results of mechanistic studies suggest a modified Piers' silane Si-H···B activation mode wherein the hydride abstraction by BEt3 is promoted by the coordination of an alkoxide or hydroxide anion to the Si center.

MANGANESE BASED COMPLEXES AND USES THEREOF FOR HOMOGENEOUS CATALYSIS

The present invention relates to novel manganese complexes and their use, inter alia, for homogeneous catalysis in (1) the preparation of imine by dehydrogenative coupling of an alcohol and amine; (2) C-C coupling in Michael addition reaction using nitriles as Michael donors; (3) dehydrogenative coupling of alcohols to give esters and hydrogen gas (4) hydrogenation of esters to form alcohols (including hydrogenation of cyclic esters (lactones) or cyclic di-esters (di- lactones), or polyesters); (5) hydrogenation of amides (including cyclic dipeptides, lactams, diamide, polypeptides and polyamides) to alcohols and amines (or diamine); (6) hydrogenation of organic carbonates (including polycarbonates) to alcohols or hydrogenation of carbamates (including polycarbamates) or urea derivatives to alcohols and amines; (7) dehydrogenation of secondary alcohols to ketones; (8) amidation of esters (i.e., synthesis of amides from esters and amines); (9) acylation of alcohols using esters; (10) coupling of alcohols with water and a base to form carboxylic acids; and (11) preparation of amino acids or their salts by coupling of amino alcohols with water and a base. (12) preparation of amides (including formamides, cyclic dipeptides, diamide, lactams, polypeptides and polyamides) by dehydrogenative coupling of alcohols and amines; (13) preparation of imides from diols.

Palladium-catalyzed [4 + 2] cycloaddition of aldimines and 1,4-dipolar equivalents via amphiphilic allylation

The combination of Pd catalyst and diethylzinc with triethylborane promotes the amphiphilic allylation of aldimines with 2,3-bismethylenebutane-1,4-diol derivatives to serve as bis-allylic zwitterion species to form 3,4-bismethylenepiperidines via a formal [4 + 2] cycloaddition reaction. 3,4-Bismethylenepiperidine rings are applicable for the synthesis of isoquinoline derivatives via the Diels-Alder reaction followed by an oxidation reaction with DDQ.