3096-47-7

Basic information

• Product Name: 2-CHLORO-9-FLUORENONE
• Synonyms: 2-Chlorofluoren-9-one
• CAS NO: 3096-47-7
• Molecular Formula: C₁₃H₇ClO
• Molecular Weight: 214.65
• Mol File: 3096-47-7.mol
• Article Data: 6

Chemical Properties

• Melting Point: 125.5°C
• Boiling Point: 308.12°C (rough estimate)
• Flash Point: 184.4°C
• Appearance: /
• Density: 1.1760 (rough estimate)
• Vapor Pressure: 7.34E-06mmHg at 25°C
• Refractive Index: 1.5260 (estimate)
• CAS DataBase Reference: 2-CHLORO-9-FLUORENONE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-CHLORO-9-FLUORENONE(3096-47-7)
• EPA Substance Registry System: 2-CHLORO-9-FLUORENONE(3096-47-7)

Safety Data

• Hazardous Substances Data: 3096-47-7(Hazardous Substances Data)

Usage

Uses

2-Chloro-9-fluorenone is a mutagenic agent towards Salmonella typhimurium.

InChI:InChI=1/C13H7ClO/c14-8-5-6-10-9-3-1-2-4-11(9)13(15)12(10)7-8/h1-7H

Upstream product

• 486-25-9 9-fluorenone 
• 51957-32-5 4-chloro-5-methyl-pyrimidine 
• 76049-50-8 2',5-dichloro-2-iodobenzophenone 
• 7012-23-9 2-chlorofluoren-9-ol 
• 41085-71-6 bromamine T 
• 89346-58-7 4′-chloro-1,1′-biphenyl-2yl-carbonitrile 
• 610-97-9 o-iodo-methyl-benzoic acid 
• 17103-28-5 methyl 4′-chloro-[1,1′-biphenyl]-2-carboxylate 
• 7079-15-4 4'-chloro-[1,1'-biphenyl]-2-carboxylic acid 
• 1679-18-1 4-Chlorophenylboronic acid 

Downstream Products

• 7012-23-9 2-chlorofluoren-9-ol 
• 109471-74-1 2-(2-nitro-anilino)-fluoren-9-one 
• 105448-93-9 7-chloro-10,10-diphenylphenanthren-9(10H)-one 
• 75783-82-3 2-chloro-9-(N-phenyl)-iminofluorene 
• 109395-69-9 2,9-Dichlor-9-phenylfluoren 
• 75784-03-1 (2-Chloro-9-phenylamino-9H-fluoren-9-yl)-phosphonic acid 
• 75783-94-7 (2-Chloro-9-phenylamino-9H-fluoren-9-yl)-phosphonic acid diethyl ester 
• 1204-44-0 2-(4-chlorophenyl)aniline 
• 188425-85-6 boscalid 

Relevant articles and documents

Palladium-catalyzed intramolecular aromatic C-H acylation of 2-arylbenzoyl fluorides

The catalytic intramolecular cyclization of acyl fluorides using a Pd(OAc)2/PCy3 system is described. A wide range of 2-arylbenzoyl fluoride derivatives can be used as fluorenone precursors and the reaction proceeds via an intramolecular coupling between aromatic C-H bonds with acyl C-F bonds. The reaction can be applied to the synthesis of indenofluorenedione derivatives and to the construction of other molecules with fivemembered rings.

Novel syntheses of fluorenones via nitrile-directed palladium-catalyzed C-H and dual C-H bond activation

Novel procedures for the [Pd]/[Ag]/TFA system catalyzed cascade reactions of nitrile directed remote C-H and dual C-H bond activation with insertion of nitrile were developed, which afforded variously polysubstituted fluorenones in moderate to good yields with tolerance of a wide variety of substrates.

2-Benzazepines. 8. Zerovalent nickel mediated biaryl synthesis of an anxiolytic pyrimido[5,4-d][2]benzazepine

-