3096-52-4 Usage
Description
2-Nitro-9-fluorenone, also known as 2-NITROFLUORENONE, is a mutagenic photoproduct derived from u.v.a.-irradiated 2-aminofluorene. It has been isolated from diesel-exhaust particles using a two-step fractionation scheme and is characterized by its bright yellow needle-like appearance. 2-NITROFLUORENONE has been quantified using advanced electrochemical techniques, such as mercury meniscus modified silver solid amalgam electrode combined with direct current voltammetry or differential pulse voltammetry.
Uses
Used in Environmental Monitoring and Analysis:
2-NITROFLUORENONE is used as a biomarker for [detecting the presence of mutagenic compounds in diesel exhaust particles] due to its isolation from these particles and its mutagenic properties.
Used in Chemical Research:
2-NITROFLUORENONE is used as a research compound for [studying the effects of u.v.a.-irradiation on 2-aminofluorene and understanding the formation of mutagenic photoproducts], which can contribute to the development of safer chemical processes and products.
Used in Pharmaceutical Industry:
2-NITROFLUORENONE is used as a starting material or intermediate for [the synthesis of various pharmaceutical compounds], given its unique chemical structure and properties.
Used in Analytical Chemistry:
2-NITROFLUORENONE is used as a reference compound for [developing and validating analytical methods], particularly those involving electrochemical techniques such as voltammetry, due to its well-defined chemical and physical properties.
Please note that the specific applications and industries for 2-NITROFLUORENONE may vary based on the context and available information. The provided uses are based on the general description and chemical properties mentioned in the materials.
Check Digit Verification of cas no
The CAS Registry Mumber 3096-52-4 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 3,0,9 and 6 respectively; the second part has 2 digits, 5 and 2 respectively.
Calculate Digit Verification of CAS Registry Number 3096-52:
(6*3)+(5*0)+(4*9)+(3*6)+(2*5)+(1*2)=84
84 % 10 = 4
So 3096-52-4 is a valid CAS Registry Number.
InChI:InChI=1/C13H7NO3/c15-13-11-4-2-1-3-9(11)10-6-5-8(14(16)17)7-12(10)13/h1-7H
3096-52-4Relevant articles and documents
Selective oxidation of aromatic amines to nitro derivatives using potassium iodide-tert-butyl hydroperoxide catalytic system
Reddy, K. Rajender,Maheswari, C. Uma,Venkateshwar,Kantam, M. Lakshmi
supporting information; experimental part, p. 93 - 96 (2009/08/07)
The direct oxidation of aromatic primary amines to the corresponding nitro compounds selectively in 47-98% yields has been achieved by using potassium iodide as catalyst and tert-butyl hydroperoxide as the external oxidant. The present catalytic system works well for both electron-rich and electron-poor substrates.
Kinetics and Mechanism of Oxidation of Fluoren-9-ol and Substituted Fluoren-9-ols by Bromamine-T
Gunasekaran, S.,Venkatasubramanian, N.
, p. 774 - 777 (2007/10/02)
The title reactions have been investigated in aq. acetic acid medium both in the presence and absence of perchloric acid.The reactions are first order each in and under both the conditions.There is unit dependence in perchloric acid.The effects of change in polarity of the solvent medium, added toluene-p-sulphonamide and sodium perchlorate have been studied.The reaction exhibits kinetic isotope effect (kH/kD = 2.2).Hammett ρ is found to be -2.8.Activation parameters have been evaluated.A mechanism consistent with rate data has been proposed.
