309757-66-2

Basic information

• Product Name: tert-butyl (E)-3-(3-iodophenyl)prop-2-enoate
• Synonyms: tert-butyl (E)-3-(3-iodophenyl)prop-2-enoate
• CAS NO: 309757-66-2
• Molecular Weight: 330.165
• Mol File: 309757-66-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: tert-butyl (E)-3-(3-iodophenyl)prop-2-enoate(CAS DataBase Reference)
• NIST Chemistry Reference: tert-butyl (E)-3-(3-iodophenyl)prop-2-enoate(309757-66-2)
• EPA Substance Registry System: tert-butyl (E)-3-(3-iodophenyl)prop-2-enoate(309757-66-2)

Safety Data

• Hazardous Substances Data: 309757-66-2(Hazardous Substances Data)

Upstream product

• 1663-39-4 tert-Butyl acrylate 
• 221037-98-5 (3-iodophenyl)boronic acid 
• 696-41-3 m-iodobenzaldehyde 
• 27784-76-5 tert-butyl diethylphosphonoacetate 

Relevant articles and documents

Rhodium-catalyzed heck-type coupling of boronic acids with activated alkenes in an aqueous emulsion

Intermolecular couplings between arylboronic acids and activated alkenes catalyzed by a water-soluble tert-bulyl amphosrhodium complex were found to progress at room temperature and generated Heck-type products with high yields and excellent selectivity. Substitution on the alkene component encouraged the formation of products arising from a conjugate addition-protonation process. In the case of Heck product formation, it was necessary to add two equivalents of the alkene component whereby one equivalent is believed to act as a sacrificial hydride acceptor.