310-17-8Relevant articles and documents
Synthesis of aryltriethoxysilanes via rhodium(I)-catalyzed cross-coupling of aryl electrophiles with triethoxysilane
Murata, Miki,Yamasaki, Hiyoruki,Ueta, Tsukasa,Nagata, Masayuki,Ishikura, Masanori,Watanabe, Shinji,Masuda, Yuzuru
, p. 4087 - 4094 (2008/01/03)
The general and efficient silylation of aryl halides has been developed utilizing triethoxysilane and a rhodium catalyst. The substrate scope is broad and includes ortho-, meta-, and para-substituted electron-rich and -deficient aryl iodides. In addition, the silylation of aryl bromides and fluoroalkanesulfonates proceeded in the presence of tetra-n-butylammonium iodide.