310-39-4Relevant articles and documents
Cleavage of the C-Si bond in trifluoro(phenyl)silane with aliphatic alcohols
Voronkov,Boyarkina,Gebel',Albanov,Basenko
, p. 1927 - 1929 (2008/02/03)
Trifluoro(phenyl)silane reacts with aliphatic alcohols under reflux. The reaction involves not only Si-F bond cleavage to form ethoxyfluoro(phenyl) silanes, but also C-Si bond cleavage to form benzene and alkoxyfluoro- and tetraalkoxysilanes. The formation of the latter products was proved by 19F and 29Si NMR spectroscopy and also by model disproportionation reactions of trifluoro(phenyl)silane with trimethoxy-(phenyl)-, tetramethoxy-, or tetraethoxysilanes.