31144-23-7Relevant articles and documents
Facile synthesis of phosphaamidines and phosphaamidinates using nitrilium ions as an imine synthon
Van Dijk, Tom,Burck, Sebastian,Rong, Mark K.,Rosenthal, Amos J.,Nieger, Martin,Slootweg, J. Chris,Lammertsma, Koop
supporting information, p. 9068 - 9071 (2014/10/15)
Readily accessible nitrilium triflates are convenient imine building blocks for the expedient synthesis of a novel class of 1,3-P,N ligands as demonstrated for the reaction with primary phosphanes. This procedure allows variation of all substituents. X-ray crystal structures are reported for nitrilium ions, phosphaamidines, and three phosphaamidinate complexes. The lithium phosphaamidinate is N coordinated and its reaction with [AuCl(tht)] (tht=tetrahydrothiophene) gives a unique P-bridged gold trimer, while a P,N-bidentate complex results from [{RhCl(cod)}2]. The nitrilium ion methodology allows extension of the 1,3-P,N motive to bis(imino)phosphanes, which are the neutral phosphorus analogues of the valuable β-diketiminate ligand.
Parallel copper catalysis: Diastereoselective synthesis of polyfunctionalized azetidin-2-imines
Xing, Yanpeng,Zhao, Hongyang,Shang, Qiongyi,Wang, Jing,Lu, Ping,Wang, Yanguang
supporting information, p. 2668 - 2671 (2013/07/19)
An efficient and diastereoselective synthesis of highly functionalized azetidin-2-imines has been achieved through a parallel catalysis strategy, including a copper-catalyzed azide-alkyne cycloaddition, a copper-catalyzed Csp-Csp2 cr
Synthesis of chlorinated bicyclic C-fused tetrahydrofuro[3,2- c ]azetidin-2-ones
Ram, Ram N.,Kumar, Neeraj,Singh, Nem
supporting information; experimental part, p. 7408 - 7411 (2011/02/22)
Some bicyclic C-fused chlorinated tetrahydrofuro[3,2-c]azetidin-2-ones were prepared by a fairly general route involving Staudinger reaction of allylic/propargylic imidates with dichloroketene followed by highly diastereoselective CuCl/PMDETA-catalyzed 5-
