3116-98-1

Basic information

• Product Name: 2,5-Cyclohexadiene-1,4-dione, 2-cyclohexyl-
• CAS NO: 3116-98-1
• Molecular Formula: C12H14O2
• Molecular Weight: 190.242
• Mol File: 3116-98-1.mol
• Article Data: 21

Chemical Properties

• CAS DataBase Reference: 2,5-Cyclohexadiene-1,4-dione, 2-cyclohexyl-(CAS DataBase Reference)
• NIST Chemistry Reference: 2,5-Cyclohexadiene-1,4-dione, 2-cyclohexyl-(3116-98-1)
• EPA Substance Registry System: 2,5-Cyclohexadiene-1,4-dione, 2-cyclohexyl-(3116-98-1)

Safety Data

• Hazardous Substances Data: 3116-98-1(Hazardous Substances Data)

Usage

General Description

2,5-Cyclohexadiene-1,4-dione, 2-cyclohexyl- is a chemical compound with the molecular formula C12H34O2. It is a crystalline solid that is commonly used as a reagent in organic synthesis. The compound is known for its strong oxidizing properties and is often used as a reagent in the preparation of various organic compounds. It is also used in the production of dyes, pharmaceuticals, and other industrial applications. The compound is considered to be toxic and should be handled with care.

Upstream product

• 105398-69-4 Cyclohexanecarboxylic acid 2-thioxo-2H-pyridin-1-yl ester 
• 106-51-4 p-benzoquinone 
• 98-89-5 Cyclohexanecarboxylic acid 
• 52033-84-8 2-cyclohexyl-1,4-dimethoxybenzene 
• 110-82-7 cyclohexane 
• 4441-56-9 cyclohexylboronic acid 
• 110-83-8 cyclohexene 
• 108-93-0 cyclohexanol 
• 123-31-9 hydroquinone 
• 126564-72-5 1,4-diacetoxy-2-cyclohexyl-benzene 
• 119-42-6 2-cyclohexylphenol 
• 626-62-0 Cyclohexyl iodide 
• 4197-75-5 cyclohexyl-1,4-benzenediol 

Downstream Products

• 1384433-60-6 2-cyclohexyl-5-(6-methyl-4-oxo-4H-chromen-3-yl)cyclohexa-2,5-diene-1,4-dione 
• 1384433-61-7 2-cyclohexyl-6-(6-methyl-4-oxo-4H-chromen-3-yl)cyclohexa-2,5-diene-1,4-dione 
• 408337-35-9 1,2,4-triacetoxy-5-cyclohexyl-benzene 

Relevant articles and documents

A direct route to isoflavan quinones. The synthesis of colutequinones A and B

The first syntheses of colutequinone A and colutequinone B were achieved. Radical generation via phenyliodoso diacetate was superior to radical generation via ammonium persulfate.

Progress towards metal-free radical alkylations of quinones under mild conditions

A new method for the radical alkylation of quinones is reported. Lewis basic nitrogen additives increase the efficacy of quinone alkylations from carboxylic acids using catalytic AgNO3 and Selectfluor as a mild oxidant. Electrochemical data sug

Quinone C-H Alkylations via Oxidative Radical Processes

A brief survey of radical additions to quinones is reported. Carboxylic acids, aldehydes, and unprotected amino acids are compared as alkyl radical precursors for the mono- or bis- C-H alkylation of several quinones. Two methods for radical initiation are discussed comparing inorganic persulfates and Selectfluor as stoichiometric oxidants. Kinetic analysis reveals dramatic differences in the rate of radical initiation depending on the identity of the radical precursor and oxidant. Synthetic strategies for efficiently producing alkyl-quinones are discussed in the context of selecting optimum radical precursors and initiators depending on quinone identity and functional groups present.