31199-21-0

Basic information

• Product Name: dioxa-3,5 exo p-nitrophenyl-4 syn tricyclo<5.2.1.0^2,6>decane
• Synonyms: dioxa-3,5 exo p-nitrophenyl-4 syn tricyclo<5.2.1.0^2,6>decane
• CAS NO: 31199-21-0
• Molecular Weight: 261.277
• Mol File: 31199-21-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: dioxa-3,5 exo p-nitrophenyl-4 syn tricyclo<5.2.1.0^2,6>decane(CAS DataBase Reference)
• NIST Chemistry Reference: dioxa-3,5 exo p-nitrophenyl-4 syn tricyclo<5.2.1.0^2,6>decane(31199-21-0)
• EPA Substance Registry System: dioxa-3,5 exo p-nitrophenyl-4 syn tricyclo<5.2.1.0^2,6>decane(31199-21-0)

Safety Data

• Hazardous Substances Data: 31199-21-0(Hazardous Substances Data)

Upstream product

• 16329-23-0 (1R,2S,3R,4S)-bicyclo[2.2.1]heptane-2,3-diol 
• 555-16-8 4-nitrobenzaldehdye 

Downstream Products

• 32819-61-7 4-Nitro-benzoic acid (1R,2S,3S,4S)-3-bromo-bicyclo[2.2.1]hept-2-yl ester 
• 77085-47-3 4-Nitro-benzoic acid (1R,2S,3R,4S)-3-hydroxy-bicyclo[2.2.1]hept-2-yl ester 
• 31112-54-6 dioxa-3,5 exo p-nitrophenyl-4 anti tricyclo<5.2.1.0^2,6> decane 
• 77085-46-2 1-[(1S,2R,6S,7R)-4-(4-Nitro-phenyl)-3,5-dioxa-tricyclo[5.2.1.0^2,6]dec-4-yl]-pyrrolidine-2,5-dione 
• 31112-53-5 doxa-3,5 exo p-methoxyphenyl-4 syn tricyclo<5.2.1.0^2,6>decane 
• 31112-53-5 dioxa-3,5 exo p-methoxyphenyl-4 anti tricyclo<5.2.1.0^2,6>decane 
• 76-84-6 triphenylmethyl alcohol 
• 77299-89-9 bromo-2 exo p-nitrobenzoyloxy-7 syn bicyclo<2.2.1>heptane 
• 77299-89-9 4-Nitro-benzoic acid (1S,2R,4S)-2-bromo-bicyclo[2.2.1]hept-7-yl ester 
• 61081-83-2 p-nitro benzoyloxy-3 tricyclo<2.2.1.0^2,6>heptane 
• 519-73-3 triphenylmethane 

Relevant articles and documents

ACTION DU N-BROMOSUCCINIMIDE SUR LES DIOXOLANNES EN SERIE BICYCLOHEPTANIQUE. LIMITATION DES TRANSPOSITIONS DE WAGNER-MEERWEIN

Vicinal benzoyloxy-trans-bicycloheptanic bromhydrins, otherwise difficult to obtain are formed from N-bromosuccinimide and norbornanes bearing a 2-aryl-1,3 dioxolane skeleton.The greater stability of the intermediate dioxolenium ion reduces the tendency towards both Wagner-Meerwein rearrangement and neighbouring group participation by chlorine, processes usually observed when a less stable intermediate is involved.Nevertheless, methoxycarbonyl neighbouring group participation and Wagner-Meerwein rearrangement occur in methoxycarbonylbicycloheptane and in a bornanic compound respectively.