31230-83-8

Basic information

• Product Name: Benzothiazole, 2,3-dihydro-2-phenyl-
• Synonyms: Benzothiazole,2,3-dihydro-2-phenyl;2-Phenyl-2,3-dihydrobenzothiazoline;2-Phenylbenzothiazoline;2-phenyl-2,3-dihydrobenzothiazole;2-phenylbenzothiazolin;2-phenylbenzothiazole
• CAS NO: 31230-83-8
• Molecular Formula: C13H11NS
• Molecular Weight: 213.303
• Mol File: 31230-83-8.mol
• Article Data: 31

Chemical Properties

• CAS DataBase Reference: Benzothiazole, 2,3-dihydro-2-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzothiazole, 2,3-dihydro-2-phenyl-(31230-83-8)
• EPA Substance Registry System: Benzothiazole, 2,3-dihydro-2-phenyl-(31230-83-8)

Safety Data

• Hazardous Substances Data: 31230-83-8(Hazardous Substances Data)

Upstream product

• 100-52-7 benzaldehyde 
• 137-07-5 2-amino-benzenethiol 
• 42152-36-3 N-(2-mercaptophenyl)benzaldimine 
• 95-16-9 1,3-Benzothiazole 
• 1141-88-4 2-Aminophenyl disulfide 
• 100-42-5 styrene 
• 210574-00-8 2,2'-disulphanediylbis(N-benzylideneaniline) 
• 3292-42-0 2-aminobenzenethiol hydrochloride 

Downstream Products

• 105117-98-4 (CH₃CO₂)3Sn(SC₆H₄NCH(C₆H₅)) 
• 883-93-2 2-Phenylbenzothiazole 
• 137-07-5 2-amino-benzenethiol 
• 1020588-44-6 [Zn(SC₆H₄NCHC₆H₅)2] 
• 634599-85-2 bis[2-(phenylmethyleneamino)benzenethiolato]palladium(II) 
• 91710-09-7 SbCl₃(C₆H₅)HCNHC₆H₄S 
• 91710-13-3 BiCl₃H(C₆H₅)CNHC₆H₄S 
• 112590-95-1 C₆H₄SNHCHC₆H₅BH₃ 
• 105117-93-9 (CH₃CO₂)2Sn(SC₆H₄NCH(C₆H₅))2 
• 86742-60-1 (OC₆H₄O)B(SC₆H₄NCHC₆H₅) 
• 19860-20-9 N-benzylidene-2-(methylsulfanyl)aniline 
• 98123-30-9 (2S,3R)-3-Phenyl-3,4-dihydro-2H-benzo[1,4]thiazine-2-carbonitrile 
• 98123-30-9 (2R,3R)-3-Phenyl-3,4-dihydro-2H-benzo[1,4]thiazine-2-carbonitrile 
• 2550-26-7 4-Phenyl-2-butanone 

Relevant articles and documents

Valence isomerization. Synthesis and characterization of cobalt and nickel complexes with non-innocent N2S2 ligand

The reactions of 2-phenylbenzothiazoline with [M(CH3COO)2]·4H2O (M = Co(II) and Ni(II)) afford the complexes [M(phbt)2] (phbt = 2- (phenylmethyleneamino)benzenethiolato) via a ring opening reaction of 2- phenylb

Surfactant mediated oxygen reuptake in water for green aerobic oxidation: Mass-spectrometric determination of discrete intermediates to correlate oxygen uptake with oxidation efficiency

A novel strategy of catalytic green aerobic oxidation by surfactant-mediated oxygen reuptake in water offers a new dimension to the applications of surfactants to look beyond as solubility aids and a conceptual advancement in understanding the role of surfactants in aquatic organic reactions through mass spectrometry guided identification of discrete intermediates.

Aerobic Dehydrogenation of N-Heterocycles with Grubbs Catalyst: Its Application to Assisted-Tandem Catalysis to Construct N-Containing Fused Heteroarenes

An aerobic dehydrogenation of nitrogen-containing heterocycles catalyzed by Grubbs catalyst is developed. The reaction is applicable to various nitrogen-containing heterocycles. The exceptionally high functional group compatibility of this method was confirmed by the oxidation of an unprotected dihydroindolactam V to indolactam V. Furthermore, by taking advantage of the oxygen-mediated structural change of the Grubbs catalyst, we integrated ring-closing metathesis and subsequent aerobic dehydrogenation to develop the novel assisted-tandem catalysis using molecular oxygen as a chemical trigger. The utility of the assisted-tandem catalysis was demonstrated by the concise synthesis of N-containing fused heteroarenes including a natural antibiotic, pyocyanine.

Peroxide-mediated oxidative coupling of primary alcohols and disulfides: Synthesis of 2-substituted benzothiazoles

A peroxide-mediated protocol for the synthesis of 2-substituted benzothiazoles was developed, starting from bis(o-aminophenyl) disulfides and primary alcohols. Eleven differently 2-substituted benzothiazoles were prepared in moderate to excellent yields using di-tert-butyl peroxide (DTBP) as an oxidant.