313-63-3Relevant articles and documents
Build-up of double carbohelicenes using nitroarenes: Dual role of the nitro functionality as an activating and leaving group
Su, Rongchuan,Yang, Yudong,You, Jingsong,Zhou, Fujian,Zhou, Fulin
, p. 7424 - 7428 (2020/09/09)
The construction of double carbohelicenes is highly fascinating yet challenging work. Disclosed herein is a streamlined and simplified synthetic route to double carbohelicenes starting from nitroarenes through sequential nitro-activated ortho-C-H arylation, denitrative alkenylation and intramolecular cyclodehydrogenation. In this synthetic strategy, the nitro group plays a dual role namely as a leaving group for the denitrative alkenylation and as an activating group for ortho-C-H arylation, which is distinct from those of aryl halides in a conventional coupling reaction. In this work, the palladium-catalyzed Heck-type alkenylation of nitroarenes has been presented, in which the conventionally inert Ar-NO2 bond is cleaved. This work provides a novel synthetic strategy for polycyclic aromatic hydrocarbons (PAHs). This journal is
Rhodaelectrocatalysis for Annulative C?H Activation: Polycyclic Aromatic Hydrocarbons through Versatile Double Electrocatalysis
Kong, Wei-Jun,Finger, Lars H.,Oliveira, Jo?o C. A.,Ackermann, Lutz
, p. 6342 - 6346 (2019/04/08)
Rapid access to structurally diversified polycyclic aromatic hydrocarbons (PAHs) in a controlled manner is of key significance in materials sciences. Herein, we describe a strategy featuring two distinct electrocatalytic C?H transformations for the synthesis of novel nonplanar PAHs. The combination of rhodaelectrooxidative C?H activation/[2+2+2] alkyne annulation of easily accessible boronic acids with electrocatalytic cyclodehydrogenation provided modular access to diversely substituted PAHs with electricity as a sustainable oxidant. The unique molecular topology as well as the photophysical and electronic properties of the thus obtained PAHs were fully analyzed. The unique power of this metallaelectrocatalysis method was demonstrated by the chemoselective assembly of synthetically useful iodo-substituted PAHs.
CONDENSED RING COMPOUND AND METHOD FOR PRODUCING THE SAME
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Paragraph 0181; 0182; 0183, (2019/01/06)
PROBLEM TO BE SOLVED: To provide a method for producing a condensed ring compound having a regioselectively introduced substituent, in a short step and with high purity. SOLUTION: The present invention provides a method for intramolecular cyclization of a compound being represented by a formula (2) and having a specific structure. SELECTED DRAWING: None COPYRIGHT: (C)2019,JPOandINPIT