31410-07-8

Basic information

• Product Name: 1-ALLYL-3-METHYLIMIDAZOLIUM BROMIDE
• Synonyms: 1-Allyl-3-methylimidazolium bromide ,99%;1-allyl-3-Methyl-1H-iMidazol-3-iuM broMide;AMIMBr;1-Allyl-3-methylimidazolium bromide >=97.0%
• CAS NO: 31410-07-8
• Molecular Formula: Br*C₇H₁₁N₂
• Molecular Weight: 203.08
• EINECS: 200-144-5
• Product Categories: Chemical Synthesis;Imidazolium;Ionic Liquids
• Mol File: 31410-07-8.mol
• Article Data: 20

Chemical Properties

• Melting Point: -52.5 °C
• Appearance: Pale yellow/Solid
• Refractive Index: n20/D 1.578
• Storage Temp.: Inert atmosphere,Room Temperature
• Sensitive: Moisture Sensitive
• CAS DataBase Reference: 1-ALLYL-3-METHYLIMIDAZOLIUM BROMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 1-ALLYL-3-METHYLIMIDAZOLIUM BROMIDE(31410-07-8)
• EPA Substance Registry System: 1-ALLYL-3-METHYLIMIDAZOLIUM BROMIDE(31410-07-8)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38
• Safety Statements: 26
• WGK Germany: 3
• F: 10-21
• Hazardous Substances Data: 31410-07-8(Hazardous Substances Data)

Usage

Chemical Properties

Colorless to dark yellow liquid

Uses

1-Allyl-3-methylimidazolium bromide can be used to prepare:A weak gel of chitin.Composite gels of chitin/cellulose.Methylimidazolium based ionic liquids with varying anions as electrolytes in graphene?nanosheet-based?supercapacitors.

InChI:InChI=1/C7H11N2.BrH/c1-3-4-9-6-5-8(2)7-9;/h3,5-7H,1,4H2,2H3;1H/q+1;/p-1

Upstream product

• 616-47-7 1-methyl-1H-imidazole 
• 106-95-6 allyl bromide 
• 74-83-9 methyl bromide 
• 31410-01-2 1-allylimidazole 

Downstream Products

• 892494-95-0 C₇H₁₄BN₂O₂⁽¹⁺⁾*Br^(1-) 
• 70529-85-0 1-methyl-3-(2-propenyl)-2(3H)-imidazolethione 
• 1234553-18-4 3-allyl-1-methylimidazolium octylsulfate 
• 1337384-31-2 Br^(1-)*C₁₀H₁₉N₂O₂S⁽¹⁺⁾ 
• 83252-46-4 PdBr₂(N₂C₃H₃CH₃)2 
• 1239277-06-5 1-allyl-3-methylimidazolium methyl phosphite 
• 1403777-45-6 [1-allyl-3-methyl-imidazol-2-ylidene]borane 
• 1442444-52-1 3-allyl-1-methylimidazolium hypophosphite 

Relevant articles and documents

1-Alkenyl-3-methylimidazolium trifluoromethanesulfonate ionic liquids: Novel and low-viscosity ionic liquid electrolytes for dye-sensitized solar cells

Dye-sensitized Solar Cells (DSCs) based on ruthenium complex N719 as sensitizer have received much attention due to their affordability and high efficiency. However, their best performance is only achieved when using volatile organic solvents as electrolyte solutions, which are unstable under prolonged thermal stress. Thus, we developed a new series of 1-alkenyl-3-methylimidazolium trifluoromethanesulfonate ionic liquids used as robust DSC electrolytes. These ionic liquids exhibit low viscosity, high conductivity, and thermal stability. The implementation of 1-but-3-enyl-3-methyl-imidazolium trifluoromethanesulfonate, [ButMIm]OTf, into DSCs gave the best photovoltaic performance. The results are fairly comparable to those reports for other popular ionic liquid electrolytes currently used in DSC field. An insightful discussion on the relationship between the structure of these new ionic liquids and the J-V characterization as well as electrochemical impedance measurement of DSCs will give more interesting information. The results are useful for large-scale outdoor application of DSCs.

Allylimidazolium halides as novel room temperature ionic liquids

Liquid state halide salts composed of imidazolium cations having allyl groups were prepared. Their ionic conductivity, viscosity, and thermal properties were investigated. Introduction of allyl group on N-position effectively suppressed the crystallizatio

Imidazolium Triflate Ionic Liquid Improves the Activity of ZnCl2 in the Synthesis of Pyrroles and Ketones

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Low viscosity azide-containing mono and dicationic ionic liquids with unsaturated side chain

A new class of azide-functionalized monocationic and unsymmetrical dicationic ionic liquids (ILs) with low viscosity and high liquid range was synthesized. All of the synthesized ILs, were characterized by FT-IR, 1HNMR, 13CNMR spectroscopies and elemental analysis. Some thermophysical properties including melting point, density, shear viscosity, decomposition temperature and heat capacity of the unsymmetrical dicationic azide functionalized IL with dicyanamide (DCA) were measured. To find the unique and general features of this dicationic IL, its properties were compared with the ones of the similar monocationic ILs. The results showed that the shear viscosity, density, thermal stability and heat capacity of the unsymmetrical dicationic IL are higher than monocationic analogues. In addition we found that the shear viscosity for the synthesized unsymmetrical dicationic IL containing azide group and DCA anion is 83.9?cP whereas the shear viscosities for other dicationic ILs reported in the literature are higher than 240?cP.