31414-54-7Relevant articles and documents
Cyclometalated metal-organic frameworks as stable and reusable heterogeneous catalysts for allylic N-alkylation of amines
Dau, Phuong V.,Cohen, Seth M.
supporting information, p. 6128 - 6130 (2013/07/26)
Metal-organic frameworks (MOFs) functionalized via Ir(i) cyclometalation are shown to be effective as heterogeneous catalysts for the allylic N-alkylation of various amines. The MOF catalysts are one of the first and most effective MOF-based heterogeneous organometallic catalysts for the direct formation of C-N bonds. In addition, these MOFs represent a rare, stable and reusable, class of reactive Ir catalysts. The Royal Society of Chemistry 2013.