314280-30-3Relevant articles and documents
Lipase catalysis in the preparation of 3-(1-amino-3-butenyl)pyridine enantiomers
Hietanen, Ari,Saloranta, Tiina,Leino, Reko,Kanerva, Liisa T.
, p. 1629 - 1632 (2013/02/22)
The kinetic resolution of 1-(3-pyridyl)buten-3-ylamine with activated and non-activated acyl donors and Burkholderia cepacia lipase (lipase PS-D) under dry conditions has been studied. The N-acylation in isopropyl acetate (E >100) and the acidic hydrolysi
Enantioselective transfer aminoallylation: Synthesis of optically active homoallylic primary amines
Sugiura, Masaharu,Mori, Chieko,Kobayashi, Shu
, p. 11038 - 11039 (2007/10/03)
A camphorquinone-derived chiral homoallylic amine was found to react with various aldehydes via imine formation and asymmetric 2-azonia-Cope rearrangement to give optically active homoallylic primary amines. A practical level of enantioselectivity with hi
Total synthesis of (S)-anabasine and (S)-anatabine
Felpin,Vo-Thanh,Robins,Villieras,Lebreton
, p. 1646 - 1648 (2007/10/03)
A chiral synthesis of (S)-anabasine and (S)-anatabine from 3-pyridinecarboxaldehyde, via a ring closing metathesis reaction (RCM) as the key step, is reported in 8 steps for both products with overall yields of 35% and 30%, respectively.