31558-46-0

Basic information

• Product Name: p-methoxybenzyl phenyl carbonate
• Synonyms: p-methoxybenzyl phenyl carbonate;Carbonic acid (4-methoxyphenyl)methylphenyl ester;4-METHOXYBENZYL PHENYL CARBONATE;RMDRWXNFPZIFDS-UHFFFAOYSA-N
• CAS NO: 31558-46-0
• Molecular Formula: C₁₅H₁₄O₄
• Molecular Weight: 258.26926
• EINECS: 250-699-3
• Mol File: 31558-46-0.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 392.9°Cat760mmHg
• Flash Point: 174.4°C
• Appearance: /
• Density: 1.184g/cm³
• Vapor Pressure: 2.21E-06mmHg at 25°C
• Refractive Index: 1.559
• CAS DataBase Reference: p-methoxybenzyl phenyl carbonate(CAS DataBase Reference)
• NIST Chemistry Reference: p-methoxybenzyl phenyl carbonate(31558-46-0)
• EPA Substance Registry System: p-methoxybenzyl phenyl carbonate(31558-46-0)

Safety Data

• Hazardous Substances Data: 31558-46-0(Hazardous Substances Data)

Usage

InChI:InChI=1/C15H14O4/c1-17-13-9-7-12(8-10-13)11-18-15(16)19-14-5-3-2-4-6-14/h2-10H,11H2,1H3

Upstream product

• 1885-14-9 phenyl chloroformate 
• 105-13-5 4-Methoxybenzyl alcohol 

Downstream Products

• 18912-37-3 4-methoxybenzyl hydrazinecarboxylate 
• 19962-28-8 4-methoxybenzyl phenyl ether 
• 4596-54-7 N-(4-methoxy-benzyloxycarbonyl)-glycine 
• 20890-93-1 N-<<(p-methoxybenzyl)oxy>carbonyl>-L-serine 
• 23234-85-7 Z(OMe)-Met-OH 
• 21209-48-3 p-methoxybenzyloxycarbonyl-Glu-OH 
• 96715-59-2 pMZ-Gly-Gly-OH 
• 25474-85-5 4-methoxybenzyloxycarbonyl azide 
• 16944-75-5 (S)-2-(4-Methoxy-benzyloxycarbonylamino)-propionic acid 
• 23234-83-5 Z(OMe)-Leu-OH 
• 20890-95-3 p-methoxybenzyloxycarbonyl-Asp-OH 
• 42533-12-0 Z(OMe)-Lys(Z)-OH 
• 23931-65-9 N,N'-Bis-(4-methoxy-benzyloxycarbonyl)-L-cystin 
• 111371-54-1 1-(4-Methoxybenzyloxycarbonyl)-2-(5-methyl-2-picolylmercapto)-1H-thieno[3,4-d]imidazole 

Relevant articles and documents

Palladium-Catalyzed Decarboxylative Carbonylative Transformation of Benzyl Aryl Carbonates: Direct Synthesis of Aryl 2-Arylacetates

A procedure on palladium-catalyzed decarboxylative alkoxycarbonylation of carbonates for the synthesis of aryl 2-arylacetates has been developed. A broad range of aryl 2-arylacetates were obtained in good yields under mild conditions under a carbon monoxide atmosphere. Interestingly, other alcohols can be added as nucleophiles as well, and the corresponding esters were also obtained in good yields.

Benzyl protection of phenols under neutral conditions: Palladium-catalyzed benzylations of phenols

Benzyl protection of phenols under neutral conditions was achieved by using a Pd(n3-C3H5)Cp-DPEphos catalyst. The palladium catalyst efficiently converted aryl benzyl carbonates into benzyl-protected phenols through the decarboxylative etherification. Alternatively, the nucleophilic substitution of benzyl methyl carbonates with phenols proceeded In the presence of the catalyst, yielding aryl benzyl ethers.