31646-28-3

Basic information

• Product Name: 4-[(methylsulfanyl)(phenyl)methylidene]morpholin-4-ium
• CAS NO: 31646-28-3
• Molecular Formula: C₁₂H₁₆NOS*I
• Molecular Weight: 222.326
• Mol File: 31646-28-3.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: 4-[(methylsulfanyl)(phenyl)methylidene]morpholin-4-ium(CAS DataBase Reference)
• NIST Chemistry Reference: 4-[(methylsulfanyl)(phenyl)methylidene]morpholin-4-ium(31646-28-3)
• EPA Substance Registry System: 4-[(methylsulfanyl)(phenyl)methylidene]morpholin-4-ium(31646-28-3)

Safety Data

• Hazardous Substances Data: 31646-28-3(Hazardous Substances Data)

Upstream product

• 2032-36-2 Thiobenzmorpholid 
• 74-88-4 methyl iodide 
• 100-52-7 benzaldehyde 

Downstream Products

• 84759-20-6 4-(α-morpholino-benzylidene)-morpholinium; iodide 
• 109142-10-1 S-methyl-1-thiobenzoylsemicarbazide 
• 2032-36-2 Thiobenzmorpholid 
• 2168-78-7 methyl dithiobenzoate 
• 121782-59-0 4-(N-phenyl-benzimidoyl)-morpholine; hydriodide 
• 17260-47-8 4-(N-benzenesulfonyl-benzimidoyl)-morpholine 
• 64906-34-9 methylsulfanyl-morpholin-4-yl-phenyl-acetonitrile 
• 31646-06-7 morpholino(phenyl)-methaneselenone 
• 52460-45-4 1-methyl-5-morpholin-4-yl-5-phenyl-5H-1λ⁴-[1,2,3,4]thiatriazole 
• 65780-61-2 4-[N-(4-amino-benzenesulfonyl)-benzimidoyl]-morpholine 
• 56353-00-5 4-(5-phenyl-1,3,4-oxadiazol-2-yl)pyridine 
• 76226-68-1 N-[1-Morpholin-4-yl-1-phenyl-meth-(Z)-ylidene]-N'-quinolin-2-yl-hydrazine; hydriodide 
• 36838-55-8 4-<α-(Methylthio)benzyl>morpholin 
• 71443-13-5 4-(methylsulfanyltriazenylidene-phenyl-methyl)-morpholine 

Relevant articles and documents

Efficient one-step synthesis of benzazoles in aqueous media

Benzazoles (benzoxazoles, benzothiazoles, and benzimidazoles) were efficiently prepared by the aquatic reaction of the corresponding thioamidinium salts and 2-aminophenol, 2-aminothiophenol, and 1,2-diaminobenzene, respectively. The thioamidinium salt was successfully applied as an alternative to a carboxylic acid derivative to react smoothly with an amino precursor and in the presence of catalytic amounts of hexadecyltrimethylammonium bromide salt to produce benzazoles in good to excellent yields. Wiley-VCH Verlag GmbH & Co. KGaA 2009.

HIGHLY COORDINATE ORGANOSILICON COMPOUNDS IN SYNTHESIS: NEW ENTRY TO S,N-ACETALS BY SELECTIVE REDUCTION OF ALKYLTHIOMETHYLENIMINIUM SALTS BY USE OF TRIMETHOXYSILANE AND DILITHIUM 2,3-BUTANDIOLATE

Reduction of alkylthiomethyleniminium iodides proceeds smoothly by use of trimethoxysilane and dilithium 2,3-butandiolate in tetrahydrofuran at 0 deg C to give the corresponding S,N-acetals selectively in high yield.

Reactions of S-Alkyl-N,N-disubstituted Thioamide Salts. Part 4. Sulphenamidine Derivatives

Readily available 3-(α-dialkylaminoalkylidene)-1-alkylthiotriazenes (1) with C-aryl, benzyl, or isopropyl substituents, on being stirred with copper(I) cyanide or copper powder in dichloromethane or toluene solution at room temperature or below, give sulp