31665-14-2

Basic information

• Product Name: 1-methoxyheptafluorocyclohexa-1,4-diene
• Synonyms: 1-methoxyheptafluorocyclohexa-1,4-diene
• CAS NO: 31665-14-2
• Molecular Weight: 236.089
• Mol File: 31665-14-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: 1-methoxyheptafluorocyclohexa-1,4-diene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-methoxyheptafluorocyclohexa-1,4-diene(31665-14-2)
• EPA Substance Registry System: 1-methoxyheptafluorocyclohexa-1,4-diene(31665-14-2)

Safety Data

• Hazardous Substances Data: 31665-14-2(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 775-51-9 octafluorocyclohexa-1,4-diene 
• 389-40-2 Pentafluoroanisole 

Relevant articles and documents

BF3-Catalyzed Fluorine Addition to Fluoro-Substituted Benzene Derivatives Using Xenon Difluoride

BF3-catalyzed room-temperature reaction of xenon difluoride with pentafluoro-substituted benzene derivatives resulted in 1,4- and 1,2-fluorine addition with regiospecificity depending on the substituent.Reaction with 1-substituted (H, Cl, Br, C6F5) pentafluorobenzene resulted in the formation of 1-substituted heptafluorocyclohexa-1,4-dienes, and reactions with n-alkoxy-substituted pentafluorobenzenes resulted in two types of 1,4-adducts, while reaction with isopropoxypentafluorobenzene resulted in the formation of hexafluorocyclohexa-2,5-dien-1-one and hexafluorocyclohexa-2,4-dien-1-one.