31679-13-7

Basic information

• Product Name: Butanedinitrile, 2,3-diphenyl-2,3-bis[(trimethylsilyl)oxy]-
• CAS NO: 31679-13-7
• Molecular Formula: C22H28N2O2Si2
• Molecular Weight: 408.648
• Mol File: 31679-13-7.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: Butanedinitrile, 2,3-diphenyl-2,3-bis[(trimethylsilyl)oxy]-(CAS DataBase Reference)
• NIST Chemistry Reference: Butanedinitrile, 2,3-diphenyl-2,3-bis[(trimethylsilyl)oxy]-(31679-13-7)
• EPA Substance Registry System: Butanedinitrile, 2,3-diphenyl-2,3-bis[(trimethylsilyl)oxy]-(31679-13-7)

Safety Data

• Hazardous Substances Data: 31679-13-7(Hazardous Substances Data)

Upstream product

• 7677-24-9 trimethylsilyl cyanide 
• 134-81-6 benzil 
• 25438-37-3 phenyl(trimethylsiloxy)acetonitrile 

Relevant articles and documents

Are multicomponent strecker reactions of diketones with diamines under high pressure amenable to heterocyclic synthesis?

Employing double Strecker strategy, two new heterocyclic compounds, 5,6,11,12-tetrahydro-6,11-dimethyldibenzo[b,f][1,4]diazocine-6,11-dicarbonitrile and 1,2,3,4,5,10-hexahydrophenazine-4a, 10a-dicarbonitrile, were prepared in one step albeit in low yields. The reaction has proven to be very limited, but such a sterically hindered amine as N-methylaniline underwent Strecker reaction with benzaldehyde and TMSCN to give the corresponding α-amino nitriles.

Synthesis of fluoroorganic O-(Trirnethylsilyl)cyanhydrines

Fluororganic and/or sterically hindered cyanohydrines are useful synthetic reagents, not readily available directly from e.g. aldehydes or ketones and hydrogen cyanide. By using trimethylsilyl cyanide (TMSCN), the obtained O-Silyl-cyanohydrines can be app