31773-64-5

Basic information

• Product Name: 5-methoxy-2-(p-tolyl)benzo[d]oxazole
• Synonyms: 5-methoxy-2-(p-tolyl)benzo[d]oxazole
• CAS NO: 31773-64-5
• Molecular Weight: 239.274
• Mol File: 31773-64-5.mol
• Article Data: 9

Chemical Properties

• CAS DataBase Reference: 5-methoxy-2-(p-tolyl)benzo[d]oxazole(CAS DataBase Reference)
• NIST Chemistry Reference: 5-methoxy-2-(p-tolyl)benzo[d]oxazole(31773-64-5)
• EPA Substance Registry System: 5-methoxy-2-(p-tolyl)benzo[d]oxazole(31773-64-5)

Safety Data

• Hazardous Substances Data: 31773-64-5(Hazardous Substances Data)

Upstream product

• 1139705-26-2 4-methylphenyl imidazolesulfonate 
• 104-87-0 4-methyl-benzaldehyde 
• 20734-76-3 2-amino-4-methoxyphenol 
• 59557-92-5 2-bromo-5-methoxyaniline 
• 874-60-2 4-methyl-benzoyl chloride 
• 104-92-7 1-bromo-4-methoxy-benzene 
• 36719-51-4 3,3-diethyl-1-(4-methylphenyl)-1-triazene 
• 106-38-7 para-bromotoluene 
• 83392-35-2 methyl 3-(4-methylphenyl)-3-oxopropanedithioate 

Downstream Products

• 72093-75-5 5-methoxy-2-(4-{4-[5-(4-methoxy-phenyl)-[1,2,4]oxadiazol-3-yl]-trans-styryl}-phenyl)-benzooxazole 
• 61519-78-6 5-methoxy-2-{4-[2-(5-methyl-2-phenyl-2H-[1,2,3]triazol-4-yl)-vinyl]-phenyl}-benzooxazole 
• 61519-75-3 5-methoxy-2-(4-{2-[2-(4-methoxy-phenyl)-2H-[1,2,3]triazol-4-yl]-vinyl}-phenyl)-benzooxazole 
• 65203-95-4 2-{4-[4-(5-chloro-2-phenyl-2H-[1,2,3]triazol-4-yl)-styryl]-phenyl}-5-methoxy-benzooxazole 
• 65204-20-8 2-{4-[4-(4-chloro-5-phenyl-[1,2,3]triazol-2-yl)-styryl]-phenyl}-5-methoxy-benzooxazole 
• 65146-15-8 5-methoxy-2-{4-[4-(4-methoxy-[1,2,3]triazol-2-yl)-styryl]-phenyl}-benzooxazole 
• 71943-91-4 2-(4-{4-[4-chloro-1-(4-chloro-phenyl)-1H-pyrazol-3-yl]-styryl}-phenyl)-5-methoxy-benzooxazole 
• 71943-97-0 2-(4-{4-[4,5-dichloro-1-(4-chloro-phenyl)-1H-pyrazol-3-yl]-styryl}-phenyl)-5-methoxy-benzooxazole 
• 71943-76-5 5-methoxy-2-{4-[4-(1-phenyl-1H-pyrazol-3-yl)-styryl]-phenyl}-benzooxazole 
• 65146-28-3 2-{4-[4-(4-chloro-5-methoxy-[1,2,3]triazol-2-yl)-styryl]-phenyl}-5-methoxy-benzooxazole 
• 59099-04-6 5-methoxy-2-{4-[4-(2-phenyl-2H-[1,2,3]triazol-4-yl)-styryl]-phenyl}-benzooxazole 
• 59099-38-6 5-methoxy-2-{4-[4-(4-phenyl-[1,2,3]triazol-2-yl)-styryl]-phenyl}-benzooxazole 
• 59098-27-0 5-methoxy-2-{4-[2-(2-phenyl-2H-[1,2,3]triazol-4-yl)-vinyl]-phenyl}-benzooxazole 
• 65204-31-1 2-{4-[4-(4,5-diphenyl-[1,2,3]triazol-2-yl)-styryl]-phenyl}-5-methoxy-benzooxazole 

Relevant articles and documents

2-Phenylbenzoxazole derivatives as solid-state fluorescence emitters: Influence of steric hindrance and hydrogen bonding on the optical properties

Six new 2-phenylbenzoxazole (PBO) derivatives, bearing either a methoxy or hydroxy group at position 5, were prepared via an efficient one-step synthesis that allowed both analogues to be obtained in equal proportions. These PBO derivatives also differed

Mixed N-heterocycles/N-heterocyclic carbene palladium(II) allyl complexes as precatalysts for direct arylation of azoles with aryl bromides

A series of mixed N-heterocycles/N-heterocyclic carbene palladium(II) allyl complexes with general formula [(NHC)Pd(η3-allyl)]2(μ2-N-heterocycles)(BF4)2 were prepared in one pot based on anion metathesis of (NHC)Pd(η3-allyl)Cl complexes and then ligand replacement with N-heterocycles [N-heterocycles = pyrazine (pyz), 4,4′-bipyridine (bpy) and trans-4,4′-bipyridylethylene (bpe)]. The solid-state structures shown dinuclear structures with two palladium(II) centers holding together by bridged N-heterocycles. Initially investigation of the obtained complexes as precatalysts for direct C[sbnd]H bond arylation of azoles with aryl bromides was carried out.

(N-heterocyclic carbene)PdCl(N-heterocyclic carboxylate) complexes: Synthesis and catalytic activities towards arylation of benzoxazoles with aryl halides

A series of N-heterocyclic carboxylate-stabilized N-heterocyclic carbene palladium complexes have been synthesized and fully characterized. The solid-state structures indicate that each of the palladium centers is coordinated by an N-heterocyclic carbene, a chloride and a bidentate N,O-donor N-heterocyclic carboxylate ligand. The catalytic performance of the complexes was screened and the results revealed that the complexes exhibit moderate to high catalytic activities for the direct C─H bond arylation of benzoxazoles with aryl bromides.