317842-43-6Relevant articles and documents
Iron-Catalyzed Diastereoselective Synthesis of Disubstituted Morpholines via C-O or C-N Bond Formation
Aubineau, Thomas,Dupas, Alexandre,Zeng, Tian,Cossy, Janine
, p. 525 - 531 (2020/08/28)
The diastereoselective synthesis of 2,6- and 3,5-disubstituted morpholines was achieved from 1,2-amino ethers and 1,2-hydroxy amines substituted by an allylic alcohol using an iron(III) catalyst. The morpholines were obtained either by C-O or C-N bond formation. A plausible mechanism is suggested, involving a thermodynamic equilibrium to explain the formation of the cis diastereoisomer as the major product.
Enantioselective nickel-catalyzedanti-arylmetallative cyclizations onto acyclic electron-deficient alkenes
Gillbard, Simone M.,Green, Harley,Argent, Stephen P.,Lam, Hon Wai
supporting information, p. 4436 - 4439 (2021/05/10)
Enantioselective nickel-catalyzed reactions of (hetero)arylboronic acids or alkenylboronic acids with substrates containing an alkyne tethered to various acyclic electron-deficient alkenes are described.
Gold-catalyzed intramolecular regio- and enantioselective cycloisomerization of 1,1-bis(indolyl)-5-alkynes
Huang, Long,Yang, Hai-Bin,Zhang, Di-Han,Zhang, Zhen,Tang, Xiang-Ying,Xu, Qin,Shi, Min
, p. 6767 - 6771 (2013/07/25)
Bis(indole) alkaloids analogues were prepared under mild conditions and in high yields through a gold-catalyzed cycloisomerization of 1,1-bis(indolyl)-5- alkynes (see scheme). The enan Copyright
