31814-77-4

Basic information

• Product Name: Benzene, [2-(ethenyloxy)ethyl]-
• Synonyms: [2-(ethenyloxy)ethyl]-benzene;(2-(vinyloxy)ethyl)benzene;Phenaethyl-vinyl-aether;vinyl 2-phenylethyl ether;phenethyl-vinyl ether;2-(vinyloxy)ethylbenzene
• CAS NO: 31814-77-4
• Molecular Formula: C10H12O
• Molecular Weight: 148.205
• Mol File: 31814-77-4.mol
• Article Data: 6

Chemical Properties

• CAS DataBase Reference: Benzene, [2-(ethenyloxy)ethyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, [2-(ethenyloxy)ethyl]-(31814-77-4)
• EPA Substance Registry System: Benzene, [2-(ethenyloxy)ethyl]-(31814-77-4)

Safety Data

• Hazardous Substances Data: 31814-77-4(Hazardous Substances Data)

Upstream product

• 108-05-4 vinyl acetate 
• 60-12-8 2-phenylethanol 
• 111-34-2 -butyl vinyl ether 
• 109-92-2 ethyl vinyl ether 

Downstream Products

• 1351397-42-6 C₂₂H₁₆O₃ 
• 1453495-45-8 (S)-2-(2-phenethoxy)propanenitrile 
• 213548-53-9 2'-O-[1-(2-phenylethoxy)ethyl]-O-(1,1,3,3-tetraisopropyldisiloxane-1,3-diyl)uridine 
• 122-71-4 acetaldehyde diphenethylacetal 

Relevant articles and documents

Access to α-Amino Acid Esters through Palladium-Catalyzed Oxidative Amination of Vinyl Ethers with Hydrogen Peroxide as the Oxidant and Oxygen Source

A novel and convenient palladium catalytic system for the synthesis of α-amino acid esters from simple starting materials is reported. Hydrogen peroxide not only acts as the green oxidant, but also as the oxygen source. This strategy for the conversion of amines and vinyl ethers into highly functionalized and structurally diverse α-amino acid esters is characterized by the simplicity of the experimental procedure, mild reaction conditions, high atom economy, scalability, and practicability.

Au(I) complexes-catalyzed transfer vinylation of alcohols and carboxylic acids

Au(I) complexes-catalyzed transfer vinylation of alcohols and carboxylic acids has been achieved. The catalyst system consists of 2 mol % AuClPPh3 and 2 mol % AgOAc. Primary alcohols and secondary alcohols were converted into corresponding vinyl ethers in good yield (64-93%); however, tertiary alcohols showed poor reactivities. Carboxylic acids were also transformed into corresponding vinyl esters in good yield (78-96%).

Acetals as New 2′-O-Protecting Functions for the Synthesis of Oligoribonucleotides: Synthesis of Uridine Building Blocks and Evaluation of Their Relative Acid Stability

A broad variety of new acyclic vinyl ethers (see 6-41) have been synthesized via the vinyl-interchange reaction of ethyl vinyl ether at room temperature using mercury(II) trifluoroacetate as a highly efficient catalyst. The appropriate vinyl ethers were r