319474-76-5 Usage
Description
(3-Chlorophenyl)acetone oxime, a member of the oxime family, is a pale yellow solid at room temperature. It is recognized for its versatility as a building block in the pharmaceutical and chemical industries, facilitating the synthesis of a wide range of compounds. Its utility extends to organic chemistry, where it serves as a reagent for preparing other derivatives. Furthermore, (3-Chlorophenyl)acetone oxime is valued as a chelating agent, effectively binding metal ions in various chemical processes. However, due to potential hazards, it is crucial to handle this compound with care, ensuring proper ventilation and the use of personal protective equipment.
Uses
Used in Pharmaceutical Industry:
(3-Chlorophenyl)acetone oxime is used as a building block for the synthesis of various pharmaceutical compounds, contributing to the development of new drugs and therapies.
Used in Chemical Industry:
(3-Chlorophenyl)acetone oxime is used as a versatile building block for the creation of a diverse array of chemical compounds, enhancing the range of products and applications within the industry.
Used in Organic Chemistry:
(3-Chlorophenyl)acetone oxime is used as a reagent in the preparation of other derivatives, expanding the possibilities for chemical reactions and product development.
Used as a Chelating Agent:
(3-Chlorophenyl)acetone oxime is used to bind metal ions in various chemical processes, improving the efficiency and effectiveness of these processes.
Check Digit Verification of cas no
The CAS Registry Mumber 319474-76-5 includes 9 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 6 digits, 3,1,9,4,7 and 4 respectively; the second part has 2 digits, 7 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 319474-76:
(8*3)+(7*1)+(6*9)+(5*4)+(4*7)+(3*4)+(2*7)+(1*6)=165
165 % 10 = 5
So 319474-76-5 is a valid CAS Registry Number.
319474-76-5Relevant articles and documents
Dynamic path bifurcation in the Beckmann reaction: Support from kinetic analyses
Yamamoto, Yutaro,Hasegawa, Hiroto,Yamataka, Hiroshi
experimental part, p. 4652 - 4660 (2011/07/29)
The reactions of oximes to amides, known as the Beckmann rearrangement, may undergo fragmentation to form carbocations + nitriles when the migrating groups have reasonable stability as cations. The reactions of oxime sulfonates of 1-substituted-phenyl-2-propanone derivatives (7-X) and related substrates (8-X, 9a-X) in aqueous CH3CN gave both rearrangement products (amides) and fragmentation products (alcohols), the ratio of which depends on the system; the reactions of 7-X gave amides predominantly, whereas 9a-X yielded alcohols as the major product. The logk-logk plots between the systems gave excellent linear correlations with slopes of near unity. The results support the occurrence of path bifurcation after the rate-determining TS of the Beckmann rearrangement/fragmentation reaction, which has previously been proposed on the basis of molecular dynamics simulations. It was concluded that path-bifurcation phenomenon could be more common than thought and that a reactivity-selectivity argument based on the traditional TS theory may not always be applicable even to a well-known textbook organic reaction.
