32019-33-3

Basic information

• Product Name: N-(3-chlorobenzylidene)-N-phenylamine oxide
• CAS NO: 32019-33-3
• Molecular Formula: C₁₃H₁₀ClNO
• Molecular Weight: 231.6776
• Mol File: 32019-33-3.mol
• Article Data: 11

Chemical Properties

• Boiling Point: 389.7°C at 760 mmHg
• Flash Point: 189.5°C
• Density: 1.253g/cm³
• Vapor Pressure: 6.29E-06mmHg at 25°C
• Refractive Index: 1.661
• CAS DataBase Reference: N-(3-chlorobenzylidene)-N-phenylamine oxide(CAS DataBase Reference)
• NIST Chemistry Reference: N-(3-chlorobenzylidene)-N-phenylamine oxide(32019-33-3)
• EPA Substance Registry System: N-(3-chlorobenzylidene)-N-phenylamine oxide(32019-33-3)

Safety Data

• Hazardous Substances Data: 32019-33-3(Hazardous Substances Data)

Upstream product

• 73662-59-6 C₁₃H₁₀ClNO*C₆N₄ 
• 2039-85-2 3-Chlorostyrene 
• 586-96-9 Nitrosobenzene 
• 587-04-2 m-Chlorobenzaldehyde 
• 100-65-2 N-Phenylhydroxylamine 
• 98-95-3 nitrobenzene 
• 100-52-7 benzaldehyde 

Downstream Products

• 73662-67-6 3-(m-chlorophenyl)-2-phenyl-5-(tricyanovinyl)-Δ⁴-1,2,4-oxadiazoline 
• 587-04-2 m-Chlorobenzaldehyde 
• 586-96-9 Nitrosobenzene 
• 1357560-75-8 C₁₉H₁₆ClNO₅ 
• 1357560-86-1 C₁₉H₁₆ClNO₅ 
• 1452777-25-1 1-tert-butyl (3R,3'R,5'R)-5'-isopropyl 3'-(3-chlorophenyl)-2-oxo-2'-phenylspiro[indoline-3,4'-isoxazolidine]-1,5'-dicarboxylate 
• 1435517-39-7 (S,E)-N-benzyl-N-((3-(3-chlorophenyl)-2-phenylisoxazolidin-4-ylidene)methyl)-4-methylbenzenesulfonamide 
• 1435517-54-6 (S,E)-3-((3-(3-chlorophenyl)-2-phenylisoxazolidin-4-ylidene)methyl)oxazolidin-2-one 
• 1435517-51-3 (S,E)-2-((3-(3-chlorophenyl)-2-phenylisoxazolidin-4-ylidene)methyl)-2,3-dihydrobenzo[d]isothiazole-1,1-dioxide 
• 1435517-40-0 (S,E)-N-(4-fluorobenzyl)-N-((3-(3-chlorophenyl)-2-phenylisoxazolidin-4-ylidene)methyl)-4-methylbenzenesulfonamide 

Relevant articles and documents

Gold-Catalyzed Oxidative Aminocyclizations of Propargyl Alcohols and Propargyl Amines to Form Two Distinct Azacyclic Products: Carbene Formation versus a 3,3-Sigmatropic Shift of an Initial Intermediate

Gold-catalyzed oxidations of propargyl alcohols with nitrones by using a P(tBu)2(o-biphenyl)Au+ catalyst, afforded bicyclic annulation products from the Mannich reactions of gold enolates. The same reactions of propargyl amines with nitrones by using the same gold catalyst gave distinct oxoarylation products. Our DFT calculations indicate that oxidation of propargyl alcohols with nitrones by using electron-rich gold catalysts lead only to gold carbenes, which can generate gold enolates or oxoarylation intermediates with enolate species having a barrier smaller than that of oxoarylation species.

Copper-Catalyzed Synthesis of Polysubstituted Pyrroles through [3+1+1] Cycloaddition Reaction of Nitrones and Isocyanides

An efficient, copper-catalyzed [3+1+1] cycloaddition reaction was developed for the expedient synthesis of pharmacologically interesting polysubstituted pyrroles from easily available nitrones and α-acidic isocyanides. The given approach features a new mo

LIC-KOR promoted nitrone reactivity: Stereoselective synthesis of highly conjugated imines and secondary amines

The reactivity of metalated alkoxy-1,3-dienes and α-aryl-N-phenylnitrones in the presence of LIC-KOR base, equimolar mixture of alkyllithium (LIC) and potassium alcoxides (KOR), (Schlosser, 1994) [1] has been studied. A cascade reaction involving a E1cb p