32054-63-0

Basic information

• Product Name: [Fe(η-cyclopentadienyl)(CO)2(GeMe3)]
• Synonyms: [Fe(η-cyclopentadienyl)(CO)2(GeMe3)]
• CAS NO: 32054-63-0
• Molecular Weight: 294.657
• Mol File: 32054-63-0.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: [Fe(η-cyclopentadienyl)(CO)2(GeMe3)](CAS DataBase Reference)
• NIST Chemistry Reference: [Fe(η-cyclopentadienyl)(CO)2(GeMe3)](32054-63-0)
• EPA Substance Registry System: [Fe(η-cyclopentadienyl)(CO)2(GeMe3)](32054-63-0)

Safety Data

• Hazardous Substances Data: 32054-63-0(Hazardous Substances Data)

Upstream product

• 137364-18-2 {Cp(CO)2FeGeMe₂GeMe₂Et} 
• 137364-17-1 {Cp(CO)2FeGeMe₂GeMe₃} 

Downstream Products

• 12078-28-3 dicarbonylcyclopentadienyliodoiron(II) 
• 1066-38-2 iodotrimethylgermane 
• 1066-37-1 trimethylbromogermane 
• 38117-54-3 cyclopentadienyl iron(II) dicarbonyl dimer 
• 865-52-1 tetramethylgermane 

Relevant articles and documents

UV photolysis of digermanyliron complexes and dynamic NMR spectroscopy of alkoxy-bridged bis(germylene)iron products

Digermanyliron complexes [Cp(CO)2FeGeMe2GeMe2R], with different terminal substituents (R = Me, Et, or OMe) have been synthesized and subjected to UV irradiation. Deoligomerization is observed to occur, initially generating a highly unstable germyl(germylene)iron complex. Where R is alkyl, a germylene is ejected to yield a germyliron complex. Where R is methoxy, internal base stabilization of the germylene moiety by the donor oxygen atom affords a methoxy-bridged bis(germylene)iron complex which is fluxional with a value of ΔG?298 for the process of germanium-oxygen bond cleavage and germylene rotation of 88.9 kJ mol-1.