32162-27-9

Basic information

• Product Name: 3-Oxatricyclo[4.1.1.02,4]octane,2,7,7-trimethyl-, (1R,2R,4S,6R)-rel-
• Synonyms: 3-Oxatricyclo[4.1.1.02,4]octane,2,7,7-trimethyl-, (1a,2b,4b,6a)-; Pinane, 2,3-epoxy-, stereoisomer (8CI); (?à)-a-Pinene oxide
• CAS NO: 32162-27-9
• Molecular Formula: C10H16 O
• Molecular Weight: 152.236
• Mol File: 32162-27-9.mol
• Article Data: 7

Chemical Properties

• Boiling Point: 188.6°Cat760mmHg
• Flash Point: 65.6°C
• Density: 1.027g/cm³
• CAS DataBase Reference: 3-Oxatricyclo[4.1.1.02,4]octane,2,7,7-trimethyl-, (1R,2R,4S,6R)-rel-(CAS DataBase Reference)
• NIST Chemistry Reference: 3-Oxatricyclo[4.1.1.02,4]octane,2,7,7-trimethyl-, (1R,2R,4S,6R)-rel-(32162-27-9)
• EPA Substance Registry System: 3-Oxatricyclo[4.1.1.02,4]octane,2,7,7-trimethyl-, (1R,2R,4S,6R)-rel-(32162-27-9)

Safety Data

• Hazardous Substances Data: 32162-27-9(Hazardous Substances Data)

Upstream product

• 80-56-8 Pinene 
• 80-56-8 rac-α-pinene 

Downstream Products

• 84569-42-6 ((1R,5S)-5-Isopropenyl-2-methyl-cyclohex-2-enyloxy)-trimethyl-silane 
• 4501-58-0 campholenyc aldehyde 
• 1197-07-5 (+/-)-trans-carveol 
• 32226-54-3 trans-sobrerol 
• 23727-15-3 (+)-campholenic aldehyde 
• 33171-49-2 isocampholenic aldehyde 
• 99-87-6 4-methylisopropylbenzene 
• 25435-53-4 (2,2,3-Trimethyl-cyclopent-3-enyl)-acetic acid 
• 1674-08-4 3-hydroxy-β-pinene 
• 7785-70-8 (+)-α-pinene 
• 473-62-1 trans-pinocamphone 
• 38235-58-4 trans-sobrerol 

Relevant articles and documents

Synthesis, characterization, magnetic and catalytic properties of a ladder-shaped MnII coordination polymer

[Mn(LH)(H2O)]n {1, where LH2- is the dianion of N-(4-carboxybenzyl)iminodiacetic acid} has been synthesized and its crystal structure has been determined. The crystal of 1 is built from 1D polymeric ladder-shaped chains that extend to a 3D supramolecular architecture through H-bonds. The compound was characterized with spectroscopic and physicochemical techniques. Variable-temperature magnetic data suggest that there are weak antiferromagnetic interactions. Compound 1 has been evaluated as a heterogeneous oxidation catalyst. It catalyzes alkene epoxidation selectively in relatively high yields. Copyright

A cheap, catalytic, scalable, and environmentally benign method for alkene epoxidations

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Photooxygenation of olefins in the presence of titanium(IV) catalyst: A convenient 'one-pot' synthesis of epoxy alcohols

The photooxygenation of olefins in the presence of transition-metal complexes derived from Ti, V, and Mo constitutes a convenient and efficient 'one-pot' synthesis of epoxy alcohols. First, singlet oxygen transforms the olefin via an ene reaction into its allylic hydroperoxide, and subsequently, the allylic hydroperoxide is converted via transition-metal-catalyzed oxygen transfer into its epoxy alcohol. From the point of view of the olefinic substrate, the oxygen transfer is intermolecular, one allylic hydroperoxide molecule serving as oxygen donor and the other as oxygen acceptor in the form of its allylic alcohol, the transition metal playing the role of a template for both as in the Sharpless epoxidation. Unlike the latter process, the hydroperoxide donor and the allylic alcohol acceptor are generated in situ and continually consumed via a novel oxygen-transfer chain sequence.