32166-40-8Relevant articles and documents
Mild and selective oxyfunctionalization of hydrocarbons by perfluorodialkyloxaziridines
DesMarteau, Darryl D.,Donadelli, Alessandro,Montanari, Vittorio,Petrov, Viacheslav A.,Resnati, Giuseppe
, p. 4897 - 4898 (1993)
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An iron catalyst for oxidation of alkyl C-H bonds showing enhanced selectivity for methylenic sites
Prat, Irene,Gomez, Laura,Canta, Merce,Ribas, Xavi,Costas, Miquel
supporting information, p. 1908 - 1913 (2013/03/14)
Many are called but few are chosen: A nonheme iron complex catalyzes the oxidation of alkyl C-H bonds by using H2O2 as the oxidant, showing an enhanced selectivity for secondary over tertiary C-H bonds (see scheme). Copyright
The selective functionalization of saturated hydrocarbons. Part 46. An investigation of Udenfriend's system under Gif conditions
Barton, Derek H.R.,Delanghe, Nathalie C.
, p. 4471 - 4476 (2007/10/03)
Under Gif conditions using ascorbic acid as reductant and oxygen as oxidant in pyridine, the selectivity for secondary hydrogen functionalization is exceptional. EDTA (ethylenediamine-tetra-acetic acid) is not needed as a ligand for iron.