321903-41-7Relevant articles and documents
Regioselectivity in the intramolecular allyl transfer reaction catalysed by electrogenerated nickel complexes: Influence of metal ions
Franco, Delphine,Du?ach, Elisabet
, p. 9289 - 9296 (2002)
The intramolecular transfer of allyl moieties from substituted allyl aryl ethers to carbonyl groups has been studied by electrosynthesis, in a nickel-catalysed reaction. The influence of metal ions such as Mg2+, Zn2+ and Al3+ has been examined. Regioselectivity towards the branched isomer was better with Zn2+ than with Mg2+ ions, but it was higher in the absence of added metal ions.