32219-13-9

Basic information

• Product Name: Naphthalene, 1-(2-nitrophenoxy)-
• CAS NO: 32219-13-9
• Molecular Formula: C16H11NO3
• Molecular Weight: 265.268
• Mol File: 32219-13-9.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: Naphthalene, 1-(2-nitrophenoxy)-(CAS DataBase Reference)
• NIST Chemistry Reference: Naphthalene, 1-(2-nitrophenoxy)-(32219-13-9)
• EPA Substance Registry System: Naphthalene, 1-(2-nitrophenoxy)-(32219-13-9)

Safety Data

• Hazardous Substances Data: 32219-13-9(Hazardous Substances Data)

Upstream product

• 90-15-3 α-naphthol 
• 577-19-5 2-nitrophenyl bromide 
• 88-73-3 2-Chloronitrobenzene 
• 1493-27-2 ortho-nitrofluorobenzene 

Downstream Products

• 239-30-5 benzo[b]naphtho[2,1-d]furan 
• 200-23-7 benzo[b]naphtho[1,8-de]pyran 
• 1519044-12-2 1-(2-iodophenoxy)naphthalene 
• 103086-58-4 1-<2-(α-naphthyloxy)phenyl carbamoyl>-4-methylpiperazine 
• 103086-57-3 N-[2-(Naphthalen-1-yloxy)-phenyl]-acetamide 
• 32219-16-2 1-(2-aminophenoxy)naphthalene 

Relevant articles and documents

A novel magnetic polyacrylonotrile-based palladium Core?Shell complex: A highly efficientcatalyst for Synthesis of Diaryl ethers

The present article describes the synthesis of a new magnetic polyacrylonitrile-based Pd catalyst involving polyacrylonitrile modified via 2-aminopyridine as an efficient support to immobilize Pd nanoparticles. The simple reusability, easy separation and high stability of this Pd complex make it an excellent candidate to generate a C–O bond via Ph-X activation which is a really important subject in achieving biologically active compounds. It is worth to note access to good and high yields as well as broad substrate scope have resulted from superior reactivity of this catalyst complex. Furthermore, the structure of the magnetic polyacrylonitrile-based heterogeneous catalyst was characterized by fourier transmission infrared (FT-IR) spectroscopy, field emission scanning electron microscopy (FE-SEM) and transmission electron microscopy (TEM), X-ray diffraction (XRD). Also, its thermal properties were studied by thermogravimetric analysis (TGA).

Access to Chiral Seven-Member Cyclic Amines via Rh-Catalyzed Asymmetric Hydrogenation

A highly efficient asymmetric hydrogenation of azepine/oxazepine-type seven-member cyclic imine hydrochlorides was successfully developed using Rh/bisphosphine-thiourea ligand ZhaoPhos, affording various chiral seven-member cyclic amines with full conversions, high yields, and excellent enantioselectivities (up to 96% yield, >99% ee). Additionally, this asymmetric hydrogenation can proceed well on gram scale with excellent ee value. Moreover, control experimental results displayed that the anion-bonding interaction between the chloride ion of the substrate and thiourea motif of the ZhaoPhos played an important role to obtain excellent enantioselectivity.

Ligand free copper-catalyzed heterogeneous O-arylation reaction under green condition

A highly porous Zn-based iso-reticular metal-organic framework (IRMOF-3) has been selected for covalent modification. Pyridine-2-aldehyde has been used to decorate the free amine group of IRMOF-3 in the porous matrix. Schiff base moiety thus generated has been availed to anchor copper(II) ions to prepare the desired catalyst that catalyzes O-arylation reactions heterogeneously under mild reaction conditions. Porous catalyst demonstrates size selectivity in products when various substrates undergo O-arylation with α and β-naphthol.