322474-84-0Relevant articles and documents
Stereocontrolled synthesis of glucosidic damascenone precursors
Yamano, Yumiko,Watanabe, Yasuko,Watanabe, Naoharu,Ito, Masayoshi
, p. 2833 - 2844 (2007/10/03)
A stereocontrolled synthesis of optically active β-D-glucopyranosides and glucosidic damascenone precursors was discussed. The method used was asymmetric transfer hydrogenation to α, β-acetylenic ketones catalyzed by chiral ruthenium complexes. To facilitate the confirmation of the stereochemistries of natural glucosides, separation of synthetic four isomers by HPCL was examined.