322641-60-1

Basic information

• Product Name: 5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)
• Synonyms: 5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)
• CAS NO: 322641-60-1
• Molecular Weight: 942.298
• Mol File: 322641-60-1.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)(CAS DataBase Reference)
• NIST Chemistry Reference: 5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)(322641-60-1)
• EPA Substance Registry System: 5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(pyridine)(322641-60-1)

Safety Data

• Hazardous Substances Data: 322641-60-1(Hazardous Substances Data)

Upstream product

• 110-86-1 pyridine 
• 13450-90-3 Gallium trichloride 
• 238402-21-6 5,10,15-tris(pentafluorophenyl)corrole 
• 238402-21-6 5,10,15-tris(2,3,4,5,6-pentafluorophenyl)corrole 

Downstream Products

• 443927-48-8 2,17-bis-formyl-5,10,15-tris-(pentafluorophenyl)corrolatogallium(III)(bis-pyridine) 
• 443927-45-5 3,17-dinitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine) 
• 443927-44-4 3-nitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine) 
• 443927-46-6 3,17,18-trinitro-5,10,15-tris-(pentafluorophenyl)corrolato gallium(III)(bis-pyridine) 
• 1160558-54-2 [(5,10,15-tris(pentafluorophenyl)corrole)Ga(pyridine)2] 
• 749216-79-3 5,10,15-tris(pentafluorophenyl)corrolate-3-carbaldehyde gallium(III) 

Relevant articles and documents

Evidence for a [17] π-Electronic Full-Fledged Non-innocent Gallium(III)-Corrole Radical

One-electron oxidation of a GaIII-corrole with N(4-BrC6H4)3SbCl6 resulted in an air-stable non-innocent GaIII-corrole radical. The single-crystal X-ray crystallography of the 2,17-bis-formyl-5,10,15-tris(pentafluorophenyl)corrolato gallium(III)(chloride) radical ([3-Cl].) revealed delocalization of the unpaired electron, which was further confirmed by electron spin resonance (ESR) spectroscopy and spin density distribution plot. In addition, the nucleus-independent chemical shift (NICS), anisotropy-induced current density (AICD) and harmonic oscillator model of aromaticity (HOMA) supported a [17] π-electron-conjugated (or antiaromatic) radical.

Gallium(III)corrole-BODIPY hybrid: Novel photophysical properties and first observation of B-F?F interactions

Anchoring a BODIPY onto Ga(iii)corrole via a meso-β linkage facilitated PeT in polar solvents, which quenched the fluorescence, and is further confirmed by electrochemical studies. The triad exhibits unprecedented crystal emission, which is not known for

Corrole and corrole functionalized silica nanoparticles as new metal ion chemosensors: A case of silver satellite nanoparticles formation

Corrole macrocycles are very appealing dyes for incorporation into light harvesting devices. This work shows the sensorial ability of 5,10,15-tris(pentafluorophenyl)corrole 1 and its monoanionic species toward Na+, Ca2+, Cu2+, Cd2+, Pb 2+, Hg2+, Ag+, and Al3+ metal ions in toluene and acetonitrile. The photophysical studies toward metal ions were carried out by absorption and emission spectroscopy. From all metal ions studied, corrole 1 shows to be colorimetric for Hg2+ allowing a naked-eye detection of Hg2+ through a change of color from purple to blue in acetonitrile and from green to yellow in toluene. In addition a new β-imine corrole 4 was successful synthesized and further functionalized with 3-isocyanatopropyl-trimethoxysilane resulting in an alkoxysilane derivative 5. The grafting of alkoxysilane derivative 5 with optically transparent silica nanoparticles (SiNPs) was achieved succesfully. The new-coated silica nanoparticles with corrole 5 were studied in the presence of Cu2+, Hg2+, and Ag+ as metal ion probes. Interestingly, upon addition of Ag+, groups of satellite AgNPs were formed around the SiNPs and were checked by transmission electron microscopy (TEM). At same time, a change of color from green to yellow was observed.