323196-10-7

Basic information

• Product Name: N-(N-benzyl-N-phenylfluorenyl-(S)-2-amino-4-pentenoyl)-(S)-valine methyl ester
• Synonyms: N-(N-benzyl-N-phenylfluorenyl-(S)-2-amino-4-pentenoyl)-(S)-valine methyl ester
• CAS NO: 323196-10-7
• Molecular Weight: 558.72
• Mol File: 323196-10-7.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-(N-benzyl-N-phenylfluorenyl-(S)-2-amino-4-pentenoyl)-(S)-valine methyl ester(CAS DataBase Reference)
• NIST Chemistry Reference: N-(N-benzyl-N-phenylfluorenyl-(S)-2-amino-4-pentenoyl)-(S)-valine methyl ester(323196-10-7)
• EPA Substance Registry System: N-(N-benzyl-N-phenylfluorenyl-(S)-2-amino-4-pentenoyl)-(S)-valine methyl ester(323196-10-7)

Safety Data

• Hazardous Substances Data: 323196-10-7(Hazardous Substances Data)

Upstream product

• 90600-20-7 (2S)-2-[(tert-butoxycarbonyl)amino]pent-4-enoic acid 
• 100-52-7 benzaldehyde 
• 323196-07-2 2-cyanoethyl N-benzyl-N-phenylfluorenyl-(S)-2-amino-4-pentenoate 
• 323196-06-1 2-cyanoethyl N-benzyl-(S)-2-amino-4-pentenoate 
• 323196-04-9 2-cyanoethyl N-tert-butyloxycarbonyl-(S)-2-amino-4-pentenoate 
• 16338-48-0 L-allylglycine 
• 5619-05-6 DL-valine methyl ester hydrochloride 
• 323196-08-3 2-cyanoethyl N-benzyl-N-phenylfluorenyl-(S)-2-amino-4-pentenoic acid 

Relevant articles and documents

N-substituted 2-amino-4-pentenoic acids for amino acid protection and resolution

N-Substituted 2-amino-4-pentenoic acid derivatives employed for the protection of racemic amino acids were shown to be capable of permitting the chromatographic separation of R and S isomers. When N(α) was disubstituted with benzyl and phenylfluorenyl groups, the racemic amino acids could be separated with facility on open silica gel columns. Further, the optically pure N-protected amino acids so derived could be used for the preparation of misacylated suppressor transfer RNAs. (C) 2000 Elsevier Science Ltd.