3240-11-7Relevant articles and documents
Palladium-Catalyzed Alkynylation and Concomitant ortho Alkylation of Aryl Iodides
Lei, Chuanhu,Jin, Xiaojia,Zhou, Jianrong
, p. 1635 - 1639 (2016)
We report an efficient alkynylation reaction of aryl iodides with simultaneous ortho-alkylaton of aryl rings. The reaction between three simple reagents - aryl halides, alkynes, and alkyl halides - formed aryl-alkynyl bonds carrying hindered aryl rings in
The Reaction of Organic Molecules on Solid Surfaces. 2. An Efficient Method for the Preparation of Deuterated Alumina.
Gaetano, Kevan,Pagni, Richard M.,Kabalka, George W.,Bridwell, Paula,Walsh, Elaine,et. al.
, p. 499 - 502 (1985)
The construction and use of simple and inexpensive device for the deuteration of alumina is described.Two methods are present for analyzing the extend of deuterating the solid: 1H NMR analysis of the water of dehydration and 1H NMR a
On the mechanism of the ruthenium-catalyzed reconstitutive condensation of allylic alcohols and terminal alkynes
Trost, Barry M.,Kulawiec, Robert J.
, p. 5579 - 5584 (1992)
The ruthenium complex (η5C5H5)(PPh3)2RuCl (1) catalyzes the addition of allylic alcohols to terminal alkynes, yielding β,γ-unsaturated ketones. The intermediacy of a ruthenium vinylidene complex is in
Casey et al.
, p. 4233,4235 (1979)
Carbon-carbon bond forming reactions with tantalum diamidophosphine complexes that incorporate alkyne ligands
Parker, Kyle D.J.,Fryzuk, Michael D.
, p. 6122 - 6131 (2014)
The incorporation of o-phenylene-linked diamidophosphine ligands onto the readily available alkyne complexes Ta(alkyne)Cl3(DME) (where alkyne = hex-3-yne or 1,2-bis(trimethylsilylacetylene); DME = 1,2-dimethoxyethane) results in the formation o
Biocatalytic Site-Selective Hydrogen Isotope Exchange of Unsaturated Fragments with D2O
Wang, Lanlan,Lou, Yujiao,Xu, Weihua,Chen, Zhichun,Xu, Jian,Wu, Qi
, p. 783 - 788 (2022/01/15)
Deuterated unsaturated fragments have gained increasing attention because of their roles in understanding reaction mechanisms and pharmaceutical potentials. Due to the difficulties of the existing synthetic methods, it is highly desirable to develop an ef
Selective Rhodium-Catalyzed Hydroformylation of Terminal Arylalkynes and Conjugated Enynes to (Poly)enals Enabled by a π-Acceptor Biphosphoramidite Ligand
Zhao, Jiangui,Zheng, Xueli,Tao, Shaokun,Zhu, Yuxin,Yi, Jiwei,Tang, Songbai,Li, Ruixiang,Chen, Hua,Fu, Haiyan,Yuan, Maolin
supporting information, p. 6067 - 6072 (2021/08/16)
The hydroformylation of terminal arylalkynes and enynes offers a straightforward synthetic route to the valuable (poly)enals. However, the hydroformylation of terminal alkynes has remained a long-standing challenge. Herein, an efficient and selective Rh-catalyzed hydroformylation of terminal arylalkynes and conjugated enynes has been achieved by using a new stable biphosphoramidite ligand with strong π-acceptor capacity, which affords various important E-(poly)enals in good yields with excellent chemo- and regioselectivity at low temperatures and low syngas pressures.