32420-34-1

Basic information

• Product Name: (4R,4aS,6R)-6-Isopropenyl-4,4a-dimethyl-1,2,3,4,4a,5,6,7-octahydro-naphthalen-1-ol
• CAS NO: 32420-34-1
• Molecular Weight: 220.355
• Mol File: 32420-34-1.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (4R,4aS,6R)-6-Isopropenyl-4,4a-dimethyl-1,2,3,4,4a,5,6,7-octahydro-naphthalen-1-ol(CAS DataBase Reference)
• NIST Chemistry Reference: (4R,4aS,6R)-6-Isopropenyl-4,4a-dimethyl-1,2,3,4,4a,5,6,7-octahydro-naphthalen-1-ol(32420-34-1)
• EPA Substance Registry System: (4R,4aS,6R)-6-Isopropenyl-4,4a-dimethyl-1,2,3,4,4a,5,6,7-octahydro-naphthalen-1-ol(32420-34-1)

Safety Data

• Hazardous Substances Data: 32420-34-1(Hazardous Substances Data)

Upstream product

• 10219-75-7 valencene 

Relevant articles and documents

The Rearrangement of Allylic Hydroperoxides Derived from (+)-Valencene

(+)-Valencene (I) reacts with triplet oxygen to give 84 percent of the secondary β-hydroperoxyde (II) and 15 percent of the α-hydroperoxide (III); reaction with singlet oxygen gives principally (ca. 80 percent) the tertiary β-hydroperoxide (IV).This undergoes a Schenck rearrangement to give suprafacially the β-hydroperoxide (II) by a non-dissociative mechanism which does not involve exchange of oxygen in an atmosphere of 18O2.The hydroperoxide (II) then undergoes a slower Smith epimerization to the α-hydroperoxide (III) by a dissociative mechanism which involves a substantial (> 55 percent) exchange.