32488-48-5

Basic information

• Product Name: BENZOPHENONE-CARBONYL-13C
• Synonyms: BENZOPHENONE-CARBONYL-13C;BENZOPHENONE-13C1 (CARBONYL-13C);benzophenone-C13
• CAS NO: 32488-48-5
• Molecular Formula: C₁₃H₁₀O
• Molecular Weight: 183.23
• Product Categories: Alphabetical Listings;B;Stable Isotopes
• Mol File: 32488-48-5.mol
• Article Data: 9

Chemical Properties

• Melting Point: 47-51 °C(lit.)
• Boiling Point: 305 °C(lit.)
• Flash Point: >230 °F
• Appearance: /
• Density: 1.087g/cm³
• Refractive Index: 1.583
• CAS DataBase Reference: BENZOPHENONE-CARBONYL-13C(CAS DataBase Reference)
• NIST Chemistry Reference: BENZOPHENONE-CARBONYL-13C(32488-48-5)
• EPA Substance Registry System: BENZOPHENONE-CARBONYL-13C(32488-48-5)

Safety Data

• Hazard Codes: Xi
• Statements: 36/37/38-52/53
• Safety Statements: 26-36-61
• WGK Germany: 3
• Hazardous Substances Data: 32488-48-5(Hazardous Substances Data)

Usage

InChI:InChI=1/C13H10O/c14-13(11-7-3-1-4-8-11)12-9-5-2-6-10-12/h1-10H/i13+1

Upstream product

• 119-61-9 benzophenone 
• 22583-75-1 (2H₁₀)benzophenone 
• 150268-30-7 benzophenone 
• 52947-05-4 [α-13C]benzoyl chloride 
• 71-43-2 benzene 
• 1111-72-4 carbon dioxide 
• 591-51-5 phenyllithium 
• 591-50-4 iodobenzene 
• 1641-69-6 [13C]Carbon monoxide 
• 98-80-6 phenylboronic acid 
• 3880-99-7 1-(13C)benzoic acid 
• 108-86-1 bromobenzene 

Downstream Products

• 119-61-9 benzophenone 
• 22583-75-1 (2H₁₀)benzophenone 
• 150268-30-7 benzophenone 
• 6933-21-7 <1-13C>-Diphenylmethan 
• 98-85-1 α-13C-α-methylbenzyl alcohol 
• 31124-35-3 <α-13C>styrene 
• 364361-00-2 1-13C-1-phenylcyclopropane 
• 37020-78-3 (α-13C)-α-methylstyrene 
• 90929-04-7 C₂₁⁽¹³⁾CH₂₁P 
• 90929-06-9 C₂₁⁽¹³⁾CH₂₂ClP 

Relevant articles and documents

Efficient synthesis of diphenylketene-13C2

A short and efficient synthesis of doubly 13C labeled diphenylketene from relatively cheap 13C labeled carbon dioxide, as the sole source of labeled carbon, is described in 22% overall yield.

Coordination behaviors of diphenylketene adsorbed in the nanocages of zeolite NaY and AgY

We investigated in detail how polar cumulene molecules like diphenylketene were accommodated in faujasite zeolite pores based on 13C CP/MAS and DD/MAS NMR analyses as well as quantum chemical calculations after adsorbing the molecule into the zeolite NaY or AgY having “hard” sodium ions or “soft” silver ions. Since the diphenylketene has such a specific structure that a carbonyl group (a hard base) is accumulated by a carbon-carbon double bond (a soft π base), which is conjugated with two benzene rings (soft π bases), it is possible for the diphenylketene to adopt multicoordination modes to different metal ions in the zeolite. Compared with the coordination modes of benzophenone and 1,1-diphenylethene adsorbed in the NaY and AgY, those of diphenylketene were identified, and specific coordination behaviors in the zeolite’s supercages were classified depending on the hard or soft metal characters: The C=O and phenyl coordination modes to Na+ in NaY prevail, while the C=C and phenyl coordination to Ag+ in AgY is favored. We also unveiled the difference in the molecular mobility depending on the types of cations in the zeolite by comparing the 13C CP/MAS and DD/MAS NMR spectra.

Synthesis of [11C]/(13C)amines via carbonylation followed by reductive animation

Twelve 11C-labelled amines were prepared via 11C-carbonylation followed by reductive amination. The 11C-carbonylation was performed in the presence of tetrakis(triphenylphosphine)palladium using aryl iodides or aryl trifla