32569-84-9Relevant articles and documents
Manganese-Catalyzed Dual-Deoxygenative Coupling of Primary Alcohols with 2-Arylethanols
Wang, Yujie,Shao, Zhihui,Zhang, Kun,Liu, Qiang
, p. 15143 - 15147 (2018/11/01)
Reported herein is a general and efficient dual-deoxygenative coupling of primary alcohols with 2-arylethanols catalyzed by a well-defined Mn/PNP pincer complex. This reaction is the first example of the catalytic dual-deoxygenation of alcohols using a non-noble-metal catalyst. Both deoxygenative homocoupling of 2-arylethanols (17 examples) and their deoxygenative cross-coupling with other primary alcohols (20 examples) proceeded smoothly to form the corresponding alkenes by a dehydrogenation and deformylation reaction sequence.
Highly Site Selective Formal [5+2] and [4+2] Annulations of Isoxazoles with Heterosubstituted Alkynes by Platinum Catalysis: Rapid Access to Functionalized 1,3-Oxazepines and 2,5-Dihydropyridines
Shen, Wen-Bo,Xiao, Xin-Yu,Sun, Qing,Zhou, Bo,Zhu, Xin-Qi,Yan, Juan-Zhu,Lu, Xin,Ye, Long-Wu
supporting information, p. 605 - 609 (2017/01/07)
Platinum-catalyzed formal [5+2] and [4+2] annulations of isoxazoles with heterosubstituted alkynes enabled the atom-economical synthesis of valuable 1,3-oxazepines and 2,5-dihydropyridines, respectively. Importantly, this Pt catalysis not only led to unique reactivity dramatically divergent from that observed under Au catalysis, but also proceeded via unprecedented α-imino platinum carbene intermediates.
Synthesis of ethoxyethynylarenes by the palladium-catalyzed reaction of aryl iodides with ethoxy(trialkylstannyl)acetylenes
Sakamoto,Yasuhara,Kondo,Yamanaka
, p. 2032 - 2035 (2007/10/02)
Palladium-catalyzed reaction of aryl and heteroaryl iodides with ethoxy(trialkylstannyl)acetylenes gave the ethoxyethynylarenes and -heteroarenes, which were easily transformed by hydration reaction into ethyl areneacetates and heteroareneacetates.