32570-09-5Relevant articles and documents
Preparation method of biomass-based 2, 5-dimethyl-N-substituted pyrrole derivative
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Paragraph 0052-0054, (2021/07/14)
The invention discloses a preparation method of a biomass-based 2, 5-dimethyl-N-substituted pyrrole derivative. The method comprises the following steps: adding 2, 5-dimethylfuran, an amine compound, a catalyst, distilled water and 2mL of solvent into a reaction kettle, and heating the reaction kettle in an oil bath pan; and obtaining the 2, 5-dimethyl-N-substituted pyrrole derivative after the temperature is 110-170 DEG C, the use amount of distilled water is 0-250 [mu] L, the use amount of the catalyst is 5-10 wt%, and the reaction time is 1-3 h. The method overcomes the defects of high cost and difficulty in separation and recovery of the existing catalyst or catalyst system.
Imidazolium Triflate Ionic Liquid Improves the Activity of ZnCl2 in the Synthesis of Pyrroles and Ketones
Nguyen, Hai Truong,Ngo, Dung Kim Thi,Chau, Khiem Duy Nguyen,Tran, Phuong Hoang
, p. 157 - 165 (2021/03/16)
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Method for preparing N-aryl pyrrole compound
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Paragraph 0021; 0049, (2020/09/09)
The present invention relates to a method for preparing an N-aryl pyrrole compound. Furan containing different substituents, aromatic amine containing different substituents and a solid Lewis acid catalyst are mixed and placed in a closed reactor, and an N-aryl pyrrole compound with different substituents is prepared under certain catalytic conditions. The reaction temperature of the catalytic reaction condition is 140-210 DEG C. The solid Lewis acid catalyst is prepared by a sol-gel method, Hf is used as a core metal element, and a mesoporous molecular sieve SBA-15 is used as a carrier. According to the method, the catalyst is simple to prepare, low in cost, high in reaction activity, good in water resistance and structural stability and high in catalytic reaction yield; meanwhile, the Lewis acid type catalyst does not generate acid protons, the corrosion of the catalyst to equipment at high temperature is avoided, the post-reaction treatment is convenient, and the catalyst is renewable and environment-friendly.