32761-45-8

Basic information

• Product Name: [Ir(I)(salicylidenephenyliminato)(1,5-cyclooctadiene)]
• CAS NO: 32761-45-8
• Molecular Weight: 496.632
• Mol File: 32761-45-8.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: [Ir(I)(salicylidenephenyliminato)(1,5-cyclooctadiene)](CAS DataBase Reference)
• NIST Chemistry Reference: [Ir(I)(salicylidenephenyliminato)(1,5-cyclooctadiene)](32761-45-8)
• EPA Substance Registry System: [Ir(I)(salicylidenephenyliminato)(1,5-cyclooctadiene)](32761-45-8)

Safety Data

• Hazardous Substances Data: 32761-45-8(Hazardous Substances Data)

Upstream product

• 779-84-0 N-phenylsalicylaldimine 
• 33087-83-1 [Ir(OMe)(1,5-cyclooctadiene)]₂ 
• 12112-67-3 bis(1,5-cyclooctadiene)diiridium(I) dichloride 

Relevant articles and documents

Iridium(I)-salicylaldiminato-cyclooctadiene complexes used as catalysts for phenylborylation

Iridium(I) salicylaldiminato-cyclooctadiene complexes, Ir(-o-O-C6H4-CH{double bond, long}N-R)(cod) (R = CH2Ph (1), Ph (2); cod = 1,5-cyclooctadiene), have been prepared, characterized and used as catalysts for arylborylation via C-H activation. With 1 as a catalyst, isolated yields of up to 91% has been achieved for the borylation of benzene by bis(pinacolato)diboron in the presence of tetra-2-pyridinylpyrazine and an ionic liquid. The catalytic system could be recycled for at least three times without loss of activity.