32766-61-3

Basic information

• Product Name: Methyl 2-(4-methoxyphenyl)-2-oxoacetate
• Synonyms: Methyl 2-(4-methoxyphenyl)-2-oxoacetate;4-Methoxy-oxo-benzeneacetic acid methyl ester
• CAS NO: 32766-61-3
• Molecular Formula: C₁₀H₁₀O₄
• Molecular Weight: 194.184
• Mol File: 32766-61-3.mol
• Article Data: 62

Chemical Properties

• Melting Point: 54 °C
• Boiling Point: 303.2±25.0 °C(Predicted)
• Appearance: /
• Density: 1.177±0.06 g/cm3(Predicted)
• CAS DataBase Reference: Methyl 2-(4-methoxyphenyl)-2-oxoacetate(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl 2-(4-methoxyphenyl)-2-oxoacetate(32766-61-3)
• EPA Substance Registry System: Methyl 2-(4-methoxyphenyl)-2-oxoacetate(32766-61-3)

Safety Data

• Hazardous Substances Data: 32766-61-3(Hazardous Substances Data)

Upstream product

• 67-56-1 methanol 
• 7099-91-4 p-methoxybenzoylformic acid 
• 23786-14-3 4-methoxy-phenyl acetic acid methyl ester 
• 6889-78-7 4'-(methoxy)-3-hydroxyflavone 
• 6971-17-1 3-hydroxy-2-(4-methoxy-phenyl)-6-methyl-chromen-4-one 
• 13305-14-1 methyl 2-hydroxy-2-(4-methoxyphenyl)acetate 
• 5781-53-3 monomethyl oxalyl chloride 
• 100-66-3 methoxybenzene 
• 17640-25-4 methyl 2,2-dichloro-2-methoxyacetate 
• 170166-55-9 2,2-Bis-benzotriazol-1-yl-2-methoxy-1-(4-methoxy-phenyl)-ethanone 
• 13139-86-1 4-methoxyphenyl magnesium bromide 
• 6832-17-3 2-diazo-1-(4-methoxyphenyl)ethanone 
• 93296-09-4 4-methoxyphenylzinc chloride 
• 82303-13-7 (4-methoxyphenyl)zinc(II) bromide 

Downstream Products

• 156-38-7 4-hydroxyphenylacetate 
• 33131-26-9 2-(4-Methoxy-phenyl)-3-methyl-but-2-enoic acid methyl ester 
• 104206-34-0 methyl (E)-α-<3-methoxy-5-oxo-4-(3,4,5-trimethoxyphenyl)-2,5-dihydrofuran-2-ylidene>(4-methoxyphenyl)acetone 
• 61418-15-3 methyl (Z)-α-<3-methoxy-5-oxo-4-(3,4,5-trimethoxyphenyl)-2,5-dihydrofuran-2-ylidene>(4-methoxyphenyl)acetone 
• 137531-85-2 (Z)-O-methylisopinastric acid 
• 22628-24-6 (E)-4-methoxy-5-(α-methoxycarbonyl-4-methoxybenzylidene)-3-phenylfuran-2(5H)-one 
• 104383-29-1 methyl (S)-α-hydroxy-(4-methoxyphenyl)acetate 
• 32174-38-2 methyl (R)-2-hydroxy-2-(4-methoxyphenyl)acetate 
• 81316-44-1 trans-2,3-bis(carbomethoxy)-p,p'-dimethoxystilbene oxide 
• 81316-37-2 cis-2,3-bis(carbomethoxy)-p,p'-dimethoxystilbene oxide 
• 75334-99-5 2,2-Dimethoxy-2-(4-methoxyphenyl)essigsaeure-methylester 
• 248582-65-2 methyl (Z)-O-methyloximino-2-(4-methoxy)phenylacetate 
• 13305-14-1 methyl 2-hydroxy-2-(4-methoxyphenyl)acetate 
• 850794-55-7 methyl 2-(4-methoxyphenyl)-2,3-epoxypropanoate 

Relevant articles and documents

Unraveling two pathways for NHPI-mediated electrocatalytic oxidation reaction

Two pathways for N-hydroxyphthalimide (NHPI)-mediated electrocatalytic oxidation using phenylacetate derivatives as template substrates were first reported for benzylic C[sbnd]H oxidation to oxygenated and non-oxygenated products. DFT calculation indicates that the hydrogen-atom transfer (HAT) process between phthalimido-N-oxyl (PINO) and substrate is a rate-determined step. Aromatic α-keto esters and 2-((1,3-dioxoisoindolin-2-yl)oxy)-2-aryl acetate obtained by cross-coupling between benzylic radical and PINO can be selectively synthesized through controlling the concentration of PINO radical. This method provides a deep understanding for selective weak C[sbnd]H oxidation using NHPI as redox mediator.

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Photoinduced Diverse Reactivity of Diazo Compounds with Nitrosoarenes

A diverse reactivity of diazo compounds with nitrosoarene in an oxygen-transfer process and a formal [2 + 2] cycloaddition is reported. Nitosoarene has been exploited as a mild oxygen source to oxidize an in situ generated carbene intermediate under visible-light irradiation. UV-light-mediated in situ generated ketenes react with nitosoarenes to deliver oxazetidine derivatives. These operationally simple processes exemplify a transition-metal-free and catalyst-free protocol to give structurally diverse α-ketoesters or oxazetidines.