32783-79-2Relevant articles and documents
Dithiocarbamate-substituted gem-difluorinated silicon reagent: generation and addition to aldehydes
Maslov, Anton S.,Smirnov, Vladimir O.,Struchkova, Marina I.,Arkhipov, Dmitry E.,Dilman, Alexander D.
, p. 5048 - 5050 (2015)
Abstract A new gem-difluorinated silicon reagent bearing a pyrrolidine dithiocarbamate substituent was prepared by the reaction of (bromodifluoromethyl)trimethylsilane with the corresponding potassium dithiocarbamate. The obtained reagent was employed in
SUBSTITUTED PYRAZOLOAZEPIN-4-ONES AND THEIR USE AS PHOSPHODIESTERASE INHIBITORS
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, (2018/07/05)
The present invention relates to novel substituted pyrazoloazepin-4-ones with phosphodiesterase inhibitory activity, as well as to their use as therapeutic agents the treatment of inflammatory diseases and conditions.
Steric Course of N5,N10-Methylenetetrahydrofolate Formation from Glycine by the Glycine Cleavage System in E. coli
Aberhart, D. John,Russell, David J.
, p. 4907 - 4910 (2007/10/02)
The steric course of the conversion of glycine to 5,10-methylenetetrahydrofolate (5,10-CH2-H4folate) by the glycine cleavage system in E. coli has been elucidated. 2-Hre of glycine is the precursor of 11-Hre of 5,10-CH2-H4folate, and 2-Hsi of glycine is the precursor of 11-Hsi of 5,10-CH2-H4folate.The overall transformation is at least 78percent stereospecific (possibly higher).