3279-17-2Relevant articles and documents
Copper-Catalyzed Hydroarylation of Internal Alkynes: Highly Regio- and Diastereoselective Synthesis of 1,1-Diaryl, Trisubstituted Olefins
Kortman, Gregory D.,Hull, Kami L.
, p. 6220 - 6224 (2017/09/15)
The copper-catalyzed hydroarylation of internal, unsymmeric alkynes is presented. Trisubstituted alkenes are obtained as single diastereomers in good to excellent yields and excellent regioselectivities. The scope of the reaction is presented with respect to alkyne and aryl iodide coupling partners. Initial mechanistic experiments indicate a hydrocupration event followed by a two-electron oxidative addition/reductive elimination pathway.
Hybrid super electron donors - Preparation and reactivity
Garnier, Jean,Thomson, Douglas W.,Zhou, Shengze,Jolly, Phillip I.,Berlouis, Leonard E. A.,Murphy, John A.
supporting information; experimental part, p. 994 - 1002 (2012/09/08)
Neutral organic electron donors, featuring pyridinylidene-imidazolylidene, pyridinylidene-benzimidazolylidene and imidazolylidene-benzimidazolylidene linkages are reported. The pyridinylidene-benzimidazolylidene and imidazolylidene-benzimidazolylidene hyb