327969-13-1

Basic information

• Product Name: isopropyl 2,3-dihydroxy-3-phenyl propanoic acid
• Synonyms: isopropyl 2,3-dihydroxy-3-phenyl propanoic acid
• CAS NO: 327969-13-1
• Molecular Weight: 224.257
• Mol File: 327969-13-1.mol
• Article Data: 5

Chemical Properties

• CAS DataBase Reference: isopropyl 2,3-dihydroxy-3-phenyl propanoic acid(CAS DataBase Reference)
• NIST Chemistry Reference: isopropyl 2,3-dihydroxy-3-phenyl propanoic acid(327969-13-1)
• EPA Substance Registry System: isopropyl 2,3-dihydroxy-3-phenyl propanoic acid(327969-13-1)

Safety Data

• Hazardous Substances Data: 327969-13-1(Hazardous Substances Data)

Upstream product

• 60512-85-8 (E)-isopropyl cinnamate 
• 79-15-2 N-bromoacetamide 
• 127-65-1 chloroamine-T 
• 7780-06-5 isopropyl cinnamate 
• 52259-82-2 α,α-dichloro-N-bromoacetamide 
• 35077-11-3 α-chloro-N-bromoacetamide 
• 28541-01-7 (Z)-isopropyl 3-phenylacrylate 

Relevant articles and documents

Enantioselective Dihydroxylation of Alkenes Catalyzed by 1,4-Bis(9-O-dihydroquinidinyl)phthalazine-Modified Binaphthyl–Osmium Nanoparticles

A series of unprecedented binaphthyl–osmium nanoparticles (OsNPs) with chiral modifiers were applied in the heterogeneous asymmetric dihydroxylation of alkenes. A remarkable size effect of the OsNPs, depending on the density of the covalent organic shells, on the reactivity and enantioselectivity of the dihydroxylation reaction was revealed. Successful recycling of the OsNPs was also demonstrated and high reaction efficiency and enantioselectivity were maintained.

Mechanistic investigation of asymmetric aminohydroxylation of alkenes

Transfer of nitrogen and oxygen in asymmetric aminohydroxylation (AA) has been examined. Electronic as well as steric effect on the nature of oxidizing agent and nitrogen source affect chemo, regio and stereoselectivity in AA reaction. A three cycle mechanistic pathway has been proposed. Results have been rationalized through an addition of alkene to Os=N bond in a [2+2] cycloaddition manner.

Catalytic asymmetric dihydroxylation of cis-disubstituted olefins

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