32804-22-1

Basic information

• Product Name: Benzenamine, 4-ethyl-N-phenyl-
• CAS NO: 32804-22-1
• Molecular Formula: C14H15N
• Molecular Weight: 197.28
• Mol File: 32804-22-1.mol
• Article Data: 20

Chemical Properties

• CAS DataBase Reference: Benzenamine, 4-ethyl-N-phenyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzenamine, 4-ethyl-N-phenyl-(32804-22-1)
• EPA Substance Registry System: Benzenamine, 4-ethyl-N-phenyl-(32804-22-1)

Safety Data

• Hazardous Substances Data: 32804-22-1(Hazardous Substances Data)

Upstream product

• 1585-07-5 1-bromo-4-ethylbenzene 
• 103-84-4 Acetanilid 
• 108-86-1 bromobenzene 
• 3663-34-1 N-(4-ethylphenyl)acetamide 
• 100-41-4 ethylbenzene 
• 622-37-7 Phenyl azide 
• 640-60-8 toluene-4-sulfonic acid phenyl ester 
• 589-16-2 4-aminoethylbenzene 
• 100-12-9 4-ethylnitrobenzene 
• 98-80-6 phenylboronic acid 
• 63139-21-9 4-ethylphenylboronic acid 
• 62-53-3 aniline 
• 5441-51-0 4-ethylcyclohexanone 
• 108-91-8 cyclohexylamine 

Relevant articles and documents

Electrochemical Reductive Arylation of Nitroarenes with Arylboronic Acids

The synthesis of diarylamine is extremely important in organic chemistry. Herein, a novel electrochemical reductive arylation of nitroarenes with arylboronic acids was developed. A variety of diarylamines were synthesized without the need for transition-metal catalysts. The reaction could be scaled up efficiently in a flow cell and several derivatization reactions were carried out smoothly. Cyclic voltammetry experiments and mechanism studies showed that acetonitrile, formic acid, and triethyl phosphite all played a role in promoting this reductive arylation transformation.

Copper-catalyzed, ceric ammonium nitrate mediated N-arylation of amines

Cu-Catalyzed, ligand- and base-free cross-coupling of aryl boronic acids with primary and secondary amines has been reported. This ‘Chan-Evans-Lam' reaction has revealed that at room temperature, with a catalytic amount of copper(ii) acetate and ceric ammonium nitrate (CAN) as an oxidant, N-arylation can result in an effective C-N bond formation. This air stable, practical, robust protocol enables tolerance towards a variety of functional groups on both boronic acid and amine partners.

Copper immobilized at a covalent organic framework: An efficient and recyclable heterogeneous catalyst for the Chan-Lam coupling reaction of aryl boronic acids and amines

A polyimide covalent organic framework (PI-COF) with high thermal and chemical stabilities has been readily prepared from commercially available and inexpensive reagents and was employed as an effective support for heterogeneous copper. It was demonstrated that the obtained Cu@PI-COF is a highly active heterogeneous catalyst which can effectively promote the Chan-Lam coupling reaction of aryl boronic acids and amines in an open flask without the aid of any base or additive. In addition, the catalyst could be readily recovered from the reaction mixture by simple filtration and reused for at least eight cycles without any observable change in structure and catalytic activity.