32832-96-5

Basic information

• Product Name: 2-PHENETHYLBENZALDEHYDE
• Synonyms: 2-PHENETHYLBENZALDEHYDE
• CAS NO: 32832-96-5
• Molecular Formula: C₁₅H₁₄O
• Molecular Weight: 210.27106
• Mol File: 32832-96-5.mol
• Article Data: 14

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 2-PHENETHYLBENZALDEHYDE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-PHENETHYLBENZALDEHYDE(32832-96-5)
• EPA Substance Registry System: 2-PHENETHYLBENZALDEHYDE(32832-96-5)

Safety Data

• Hazardous Substances Data: 32832-96-5(Hazardous Substances Data)

Upstream product

• 304674-02-0 bibenzyl-2-carbanilide 
• 119391-25-2 C₂₂H₂₁N₂O₃S^(1-)*Na⁽¹⁺⁾ 
• 161521-66-0 trans-2-<(N-methylamino)methyl>stilbene 
• 32832-91-0 1-(2-Phenethyl-benzyl)-3,5,7-triaza-1-azonia-tricyclo[3.3.1.1^3,7]decane; bromide 
• 835-78-9 [2-(2-phenylethyl)phenyl]methanol 
• 194418-09-2 1-Diazomethyl-2-phenethyl-benzene 
• 194418-07-0 2-(2-phenylethyl)benzaldehyde tosylhydrazone 
• 201230-82-2 carbon monoxide 
• 103-29-7 1,1'-(1,2-ethanediyl)bisbenzene 
• 4890-85-1 o-phenethylbenzoic acid 
• 86769-97-3 (E)-N-methyl-2-styrylbenzamide 
• 79-37-8 oxalyl dichloride 
• 26260-02-6 2-iodobenzaldehyde 
• 17376-04-4 2-phenethyl iodide 

Downstream Products

• 1268267-70-4 1,3-dimethyl-5-(2-phenethylbenzylidene)pyrimidine-2,4,6(1H,3H,5H)-trione 
• 1268267-86-2 1',3'-dimethyl-3-phenyl-3,4-dihydro-1H,1'H-spiro[naphthalene-2,5'-pyrimidine]-2',4',6'(3'H)-trione 
• 1391990-55-8 C₂₂H₂₁NO₂S 
• 1392836-18-8 2-((2R,4S)-1,2,3,4-tetrahydro-6-methoxy-2-phenethylquinolin-4-yl)phenol 
• 1182624-36-7 2-(4-methylbenzenesulfonyl)-3-phenyl-1,2,3,4-tetrahydroisoquinoline 
• 833-48-7 dibenzosuberane 
• 4890-85-1 o-phenethylbenzoic acid 

Relevant articles and documents

Enantioselective Remote C(sp3)-H Cyanation via Dual Photoredox and Copper Catalysis

The remote C(sp3)-H cyanation of carboxamides has been described by merging photoredox and copper catalysis in a site-selective and enantiocontrolled manner. The protocol is the integration of photoinduced and nitrogen-centered radical-mediated intermolecular hydrogen atom transfer with chiral copper-complex-catalyzed radical cyanation. This strategy gives enantio-enriched cyanated amides in high yields.

Rhodium-catalyzed intramolecular hydroacylation of 1,2-disubstituted alkenes for the synthesis of 2-substituted indanones

The intramolecular hydroacylation of 1,2-disubstituted alkenes was considered to be a challenging task due to the side reactions resulted from the lack of additional substituent at 1-position and the low activity caused by the steric hindrance of substituent at 2-position, and an asymmetric version has not been considered possible due to problems associated with the racemization of the products. We have partially solved these problems. Catalyzed by an activated diphosphine-Rh complex and reacted in a selected dihalogenated solvent, the intramolecular hydroacylation of o-(2-arylvinyl)benzaldehydes provided the corresponding 2-aryl-1-indanones in high yields, and its asymmetric variant using o-(2-alkylvinyl)benzaldehydes afforded chiral 2-alkyl-1-indanones in high yields and with moderate enantioselectivities.

Transformation of Trifluorotoluenes Triggered by Titanium(IV) Chloride-Catalyzed Hydrodefluorination using Hydrosilanes

The titanium tetrachloride-catalyzed hydrodefluorination reaction of trifluorotoluene derivatives was developed using triethylsilane as the reducing agent. The reaction produced various toluene derivatives with high chemoselectivities by means of readily accessible reagents. This hydrodefluorination process was extended to the intramolecular Friedel-Crafts benzylation reaction, furnishing polycyclic aromatics of various ring sizes in good yields.