328394-37-2Relevant articles and documents
Oxabicyclo[3.2.1]octenes in Organic Synthesis - Direct Ring Opening of Oxabicyclo[3.2.1] Systems Employing Silyl Ketene Acetals in Concentrated Solutions of Lithium Perchlorate-Diethyl Ether: Application to the Synthesis of the C(19)-C(27) Fragment of Rif
Hunt, Kevin W.,Grieco, Paul A.
, p. 481 - 484 (2001)
(Matrix Presented) The direct opening at the bridgehead of oxabicyclo[3.2.1]octenes employing silyl ketene acetals in 4.0-5.0 M lithium perchlorate in diethyl ether has been realized, which gives rise to highly functionalized cycloheptadienes that can be