32849-13-1

Basic information

• Product Name: 2,3-anhydro-4,6-O-benzylidene-α-D-mannopyranosyl 4,6-O-benzylidene-α-D-glucopyranoside
• CAS NO: 32849-13-1
• Molecular Weight: 500.502
• Mol File: 32849-13-1.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 2,3-anhydro-4,6-O-benzylidene-α-D-mannopyranosyl 4,6-O-benzylidene-α-D-glucopyranoside(CAS DataBase Reference)
• NIST Chemistry Reference: 2,3-anhydro-4,6-O-benzylidene-α-D-mannopyranosyl 4,6-O-benzylidene-α-D-glucopyranoside(32849-13-1)
• EPA Substance Registry System: 2,3-anhydro-4,6-O-benzylidene-α-D-mannopyranosyl 4,6-O-benzylidene-α-D-glucopyranoside(32849-13-1)

Safety Data

• Hazardous Substances Data: 32849-13-1(Hazardous Substances Data)

Upstream product

• 32849-09-5 4,6:4'6'-di-O-benzylidene-α,α-trehalose 2-tosylate 
• 18929-82-3 4,6-O-benzylidene-α-D-glucopyranosyl-(1→1)-4',6'-O-benzylidene-α-D-glucopyranoside 
• 2232-08-8 N-tosylimidazole 

Downstream Products

• 97398-94-2 Acetic acid (4aR,6R,7R,8S,8aR)-7-acetoxy-6-((4aR,6R,7S,8aS)-7-acetoxy-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-6-yloxy)-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxin-8-yl ester 
• 97390-03-9 4,6-benzylidene-3-deoxy-α-D-arabino-hexopyranosyl 4,6-benzylidene-α-D-glucopyranoside 

Relevant articles and documents

SYNTHESIS OF 2-DEOXY, 3-DEOXY, AND 2,3-DIDEOXY ANALOGS OF α,α-TREHALOSE BY REDUCTIVE DESULFONYLOXYLATION OF p-TOLUENESULFONATES WITH LITHIUM TRIETHYLBOROHYDRIDE

Lithium triethylborohydride reacts readily with the 2-tosylate, the 2,2'-ditosylate, the 2,3,2'-tritosylate, and the 2,3,2',3'-tetratosylate of 4,6:4',6-di-O-benzylidene-α,α-trehalose (1), to give products resulting both from O-desulfonylation and from re