329003-67-0

Basic information

• Product Name: 6'-phenyl-5,6-pinene-2,2'-bipyridine
• Synonyms: 6'-phenyl-5,6-pinene-2,2'-bipyridine
• CAS NO: 329003-67-0
• Molecular Weight: 326.441
• Mol File: 329003-67-0.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: 6'-phenyl-5,6-pinene-2,2'-bipyridine(CAS DataBase Reference)
• NIST Chemistry Reference: 6'-phenyl-5,6-pinene-2,2'-bipyridine(329003-67-0)
• EPA Substance Registry System: 6'-phenyl-5,6-pinene-2,2'-bipyridine(329003-67-0)

Safety Data

• Hazardous Substances Data: 329003-67-0(Hazardous Substances Data)

Upstream product

• 59576-29-3 methyl(2-phenylpyridin-6-yl)-methanone 
• 49669-13-8 1-(6-bromopyridin-2-yl)-ethanone 
• 626-05-1 2,6-Dibromopyridine 

Downstream Products

• 608517-46-0 (C₆H₅C₅H₃NC₁₀H₇N(CH₃)2CH₂)2C₆H₄ 

Relevant articles and documents

Enantioselective catalytic cyclopropanation of styrenes by copper complexes with chiral pinene-[5,6]-bipyridine ligands

Substituted mono- and bis-pinene-[5,6]-bipyridines are useful ligands in asymmetric copper-catalyzed cyclopropanation by styrenes. Copper complexes were prepared either in situ or prior to the reaction. The catalytic reaction of styrene with ethyl diazoacetate and Cu-11b yields ethyl trans-phenylcyclopropane carboxylate in >99% yield and 87% e.e. at 0°C. The corresponding cis-configured cyclopropane was produced with an e.e. of 90%. The cis/trans ratio is 22:78. Other ligands of this series are less effective. Various olefins were tested as substrates but exo-methylene olefins show the best results. (C) 2000 Elsevier Science Ltd.